Effect of (Ge) addition on mechanical properties of (Ti12Mo5Ta) alloy used in biomedical applications
DOI:
https://doi.org/10.62638/ZasMat1243Apstrakt
The primary objective of this investigation is to examine the impact of adding (Ge) to the Ti12Mo5Ta alloy on its compressive strength, hardness, and elastic modulus. A Ti-Mo-Ta alloy with an 83% Ti, 12% Mo, and 5% Ta composition was synthesized by powder metallurgy, with the inclusion of Ge. The mixing procedure lasted for a duration of 5 hours, with a compacting pressure of 800MPa applied to create a disk sample. After the compaction step, the samples were sintered by gradually increasing the temperature to 950 ºC at a rate of 10 ˚C/min, which took a total of 7 hours. The addition of (Ge) is done in different weight percentages, ranging from 0.5% to 5%.The impact of (Ge) was examined using X-ray diffraction. The addition of 0.5% to 5% (Ge) enhances the compressive strength of the Ti12Mo5Ta alloy. Similarly, the macro hardness of the alloy increases with higher Ge content.Conversely the inclusion of 0.5% to 5% (Ge) causes a decrease in the elastic modulus of the Ti12Mo5Ta alloy.
Ključne reči:
biomaterials, Compressive Strength, Macro hardness, Elastic Modules, orthopedics.Reference
Al-Humairi, A.N.S., et al., BIOMATERIALS: A Multidisciplinary approaches and theirrelated applications. White Falcon Publishing.
Vallet-Regí, M.J.C.R.C., Evolution of bioceramics within the field of biomaterials. 2010. 13(1-2): p. 174-185.
https://doi.org/10.1016/j.crci.2009.03.004
Kunčická, L., Kocich, R., & Lowe, T. C. (2017). Adv nces in met ls and alloys for joint replacement. Progress in Materials Science, 88, 232-280.
https://doi.org/10.1016/j.pmatsci.2017.04.002
Ostomel, T. A., Shi, Q., Tsung, C. K., Liang, H., & Stucky, G. D. (2006). Spherical bioactive glass with enhanced rates of hydroxyapatite deposition and hemostatic activity. Small, 2(11), 1261-1265..
https://doi.org/10.1002/smll.200600177
Y. Li, C. Yang, H. Zhao, S. Qu, X. Li, and Y. Li, "New developments of Ti-based alloys for biomedical applications," Materials, vol. 7, pp. 1709-1800, 2014.
https://doi.org/10.3390/ma7031709
Q. Chen and G. A. Thouas, "Metallic implant biomaterials," Materials Science and Engineering: R: Reports, vol. 87, pp. 1-57, 2015.
https://doi.org/10.1016/j.mser.2014.10.001
Chakraborty, R., Seesala, V. S., Sen, M., Sengupta, S., Dhara, S., Saha, P., ... & Das, S. "MWCNT reinforced bone like calcium phosphate-Hydroxyapatite composite coating developed through pulsed electrodeposition with varying amount of apatite phase and crystallinity to promote superior osteoconduction, cytocompatibility and corrosion protection performance compared to bare metallic implant surface". (2017). Surface and Coatings Technology, 325, 496-514.
https://doi.org/10.1016/j.surfcoat.2017.06.073
M. Long and H. J. Rack, "Titanium alloys in total joint replacement-a materials science perspective," Biomaterials, vol. 19, pp. 1621-1639, 1998.
https://doi.org/10.1016/S0142-9612(97)00146-4
T. Hanawa, "Recent development of new alloys for biomedical use," in Materials science forum, 2006, pp. 243-248.
https://doi.org/10.4028/0-87849-996-2.243
M. A. Hussein, A. S. Mohammed, and N. Al-Aqeeli, "Wear characteristics of metallic biomaterials: a review," Materials, vol. 8, pp. 2749-2768, 2015.
https://doi.org/10.3390/ma8052749
V. Oliveira, R. Chaves, R. Bertazzoli, and R. Caram, "Preparation and characterization of Ti-Al-Nb alloys for orthopedic implants," Brazilian Journal of Chemical Engineering, vol. 15, pp. 326-333, 1998.
https://doi.org/10.1590/S0104-66321998000400002
Y. T. Zhu, T. C. Lowe, R. Z. Valiev, V. V. Stolyarov, V. V. Latysh, and G. J. Raab, "Ultrafine-grained titanium for medical implants," ed: Google Patents, 2002.
N. More, N. Diomidis, S. Paul, M. Roy, and S. Mischler, "Tribocorrosion behavior of β titanium alloys in physiological solutions containing synovial components," Materials Science and Engineering: C, vol. 31, pp. 400-408, 2011.
https://doi.org/10.1016/j.msec.2010.10.021
R. Banerjee, S. Das, K. Mukhopadhyay, S. Nag, A. Chakrabortty, and K. Chaudhuri, "Involvement of in vivo induced cheY‐4 gene of Vibrio cholerae in motility, early adherence to intestinal epithelial cells and regulation of virulence factors," FEBS letters, vol. 532, pp. 221-226, 2002.
https://doi.org/10.1016/S0014-5793(02)03678-5
S. Gross and E. Abel, "A finite element analysis of hollow stemmed hip prostheses as a means of reducing stress shielding of the femur," Journal of Biomechanics, vol. 34, pp. 995-1003, 2001.
https://doi.org/10.1016/S0021-9290(01)00072-0
M. Geetha, A. Singh, R. Asokamani, and A. Gogia, "Ti based biomaterials, the ultimate choice for orthopaedic implants-a review," Progress in Materials science, vol. 54, pp. 397-425, 2009.
https://doi.org/10.1016/j.pmatsci.2008.06.004
M. Niinomi, M. Nakai, and J. Hieda, "Development of new metallic alloys for biomedical applications," Acta Biomaterialia, vol. 8, pp. 3888-3903, 2012
https://doi.org/10.1016/j.actbio.2012.06.037
D. Banerjee and J. Williams, "Perspectives on titanium science and technology," Acta Materialia, vol. 61, pp. 844-879, 2013.
https://doi.org/10.1016/j.actamat.2012.10.043
S. Kumar and T. S. Narayanan, "Corrosion behaviour of Ti-15Mo alloy for dental implant applications," Journal of Dentistry, vol. 36, pp. 500-507, 2008.
https://doi.org/10.1016/j.jdent.2008.03.007
R.Prakash kolli and Arun Davaraj, "A Review of Metastable Beta Titanium Alloys," MDPI, 2018.
Carsten Siemers and Christian Stocker , " Develpments in Titanium Research and Applicatin in Germany," MATEC Web of Cnferences, 2020.
https://doi.org/10.1051/matecconf/202032101003
ASTM, N. "Standard practice for microetching metals and alloys." Unided Stated of America: ASTM (2005).
Ammar Hassan Khilfa, (2015) 'Effect of Y and Ge addition on Mechanical properties and Corrosion behavior of Biomedical CoCrMo Alloy (F75)', MSC thesis, Submitted to the Council of the College of Materials engineering / University of Babylon.
Al-Maamoria, M., J.M. Salmana, and O. Ihsana, Testing the Mechanical Properties of the Alloy (Al-Cu-Mg) by Ultrasonic Technology. 2013.
Huber, D.E. (2016) 'Structure and Properties of Titanium Tantalum Alloys for Biocompatibility', PhD thesis, The Ohio State University.
I.J. Beyerlein and L.S. Tóth: Texture evolution in equal-channel angular extrusion. Prog. Mater. Sci. 54, 427 (2009).
https://doi.org/10.1016/j.pmatsci.2009.01.001
M.R. Bache and W.J. Evans: Impact of texture on mechanical properties in an advanced titanium alloy. Mater. Sci. Eng., A 319-321, 409 (2001).