An evaluation of wood ashes as an eco-friendly environmentally corrosion inhibitor for low carbon steel in acidic solution at different temperatures
DOI:
https://doi.org/10.62638/ZasMat1236Apstrakt
Corrosion is an unavoidable fact in everyday life but always receive attention to control due to its technical, economical, and esthetical importance. Carbon steel (CS) is the most commonly used material for equipment and pipes in the oil production processes. However, presence of water/salts and carbon dioxide, among other gases, in the oil is a serious problem due to increased corrosion rate of the material. The most common way of mitigating this problem is by using corrosion inhibitors. However, many common corrosion inhibitors that are in use today are health hazards. Corrosion inhibitors are one of the most widely used and economically viable methods protecting metals and alloys against corrosion. In this work the inhibitory effect of wood ash (olive and palm) on mild carbon steel was studied in a solution of 0.00001 M or pH around 5 of hydrochloric acid.The corrosion rate and inhibitor efficiency were calculated by conducting the inhibition efficiency test for 10% aqueous wood ash solutions for both (olive and palm) using (weight loss method).The effect of temperature on the corrosion behavior of mild carbon steel was studied at 0.00001 M and pH = 5 hydrochloride with the addition of 10% aqueous wood ash solutions (olive and palm) in the temperature range 25-50 degrees Celsius.An inhibition efficiency of up to 54.16 % for Palm Ash Solution and 48.18 % for Olive Ash Solution can be obtained. The interaction between the corrosion rate of mild steel and the inhibitor is affected by temperature and the protection mechanism of wood ash solution is more efficient at higher temperatures. This is due to corrosion of the metal or damage that occurs on its surface due to high temperatures. It occurs at non-adsorbed sites of inhibitory elements. As for the adsorbed sites, the interaction between the active substance of the inhibitor and the surface occurs gradually with increasing temperatures, which leads to an increase in the efficiency of the inhibitor.
Ključne reči:
Corrosion Inhibitors; Carbon Steel; Palm Ash; Olive Ash; Hydrochloric Acid; inhibition efficiency.Reference
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