Enhancing epoxy nanocomposites with mineral nanofillers:A comprehensive review of particle size, shape, and concentration
DOI:
https://doi.org/10.62638/ZasMat1554Abstract
Mineral nanofillers have emerged as promising reinforcements for epoxy nanocomposites, offering enhanced mechanical, thermal, and physical properties of the latter. This review comprehensively explores the influence of mineral nanofiller morphology, surface modification, and loading on the performance of epoxy nanocomposites. The size and shape of nanoparticles significantly affect the interfacial interactions and dispersion within the epoxy matrix, with smaller particles and higher aspect ratios generally leading to improved properties. Surface modification techniques, such as the use of coupling agents, polymer grafting, and functionalization, are crucial for optimizing the compatibility and bonding between nanofillers and epoxy matrix. The loading concentration of mineral nanofillers plays a critical role in determining the final properties of nanocomposites, with optimal loadings varying depending on the specific nanofiller and the desired enhancements. Key mineral nanofillers, including nano-silica, nano-clay, nano-calcium carbonate (CaCO3), and nano-talc, have demonstrated remarkable improvements in mechanical strength, thermal stability, and barrier properties when incorporated into epoxy matrix. This review provides valuable insights into the complex interplay between nanofiller characteristics and epoxy nanocomposite performance, guiding the design and development of advanced materials for various applications.
Keywords:
Epoxy composites, Mineral nanofillers, Particle size, Particle shape, Morphology, Surface modification, Filler Loading, Nano-silica, Nano-clay, Nano-CaCO3, Nano-TalcReferences
J.J. Fekiač, M. Krbata, M. Kohutiar, R. Janík, L. Kakošová, A. Breznická, M. Eckert, P. Mikuš (2025) Comprehensive Review: Optimization of Epoxy Composites, Mechanical Properties, & Technological Trends, Polymers, 17 (3), 271. https://doi.org/10.3390/polym17030271 DOI: https://doi.org/10.3390/polym17030271
M. Zhang, M. Zhang, D. Jiang, Z. Guo, Z. Zhai, Z. Wu, M. Li, Z. Wu, C. Wang, T. Cheng, L. Chen (2016) Epoxy nanocomposites with carbon nanotubes and montmorillonite: Mechanical properties and electrical insulation, Journal of Composite Materials, 50 (24), 3363–3372. https://doi.org/10.1177/0021998315620000 DOI: https://doi.org/10.1177/0021998315620000
S. Barrau, C. Lacabanne, P. Demont, A. Peigney, C. Laurent (2003) DC and AC Conductivity of Carbon Nanotubes−Polyepoxy Composites, Macromolecules, 36 (14), 5187–5194. https://doi.org/10.1021/ma021263b DOI: https://doi.org/10.1021/ma021263b
A. Yahyazadeh, S. Nanda, A.K. Dalai (2024) Carbon Nanotubes: A Review of Synthesis Methods and Applications, Reactions 5 (3), 429–451. https://doi.org/10.3390/reactions5030022 DOI: https://doi.org/10.3390/reactions5030022
A.R. Kamali (2016) Eco-friendly production of high quality low cost graphene and its application in lithium ion batteries, Green Chemistry, 18 (7),1952–1964. https://doi.org/10.1039/c5gc02455b DOI: https://doi.org/10.1039/C5GC02455B
Q. Zhang, Y. Zhang, J. Huang, F. Wei, W. Qian (2013) The Road for Nanomaterials Industry: A Review of Carbon Nanotube Production, Post‐Treatment, and Bulk Applications for Composites and Energy Storage, Small, 9 (8), 1237–1265. https://doi.org/10.1002/smll.201203252 DOI: https://doi.org/10.1002/smll.201203252
Y. Sato, F. Watari, K.-I. Shibata, A. Yokoyama, K. Tohji (2006) Safeness of carbon nanotubes, TANSO, 2006 (225), 364–372. https://doi.org/10.7209/tanso.2006.364 DOI: https://doi.org/10.7209/tanso.2006.364
A. Zeinedini, M.M. Shokrieh (2024) Agglomeration phenomenon in graphene/polymer nanocomposites: Reasons, roles, and remedies, Applied Physics Reviews, 11 (4). https://doi.org/10.1063/5.0223785 DOI: https://doi.org/10.1063/5.0223785
H. Du, G.J. Weng, J. Zhang, C. Fang (2022) Modeling the evolution of graphene agglomeration and the electrical and mechanical properties of graphene/polypropylene nanocomposites, Journal of Applied Polymer Science, 140 (2), e53292. https://doi.org/10.1002/app.53292 DOI: https://doi.org/10.1002/app.53292
I. Alameri, M. Oltulu (2020) Mechanical properties of polymer composites reinforced by silica-based materials of various sizes, Applied Nanoscience, 10 (11), 4087–4102. https://doi.org/10.1007/s13204-020-01516-6 DOI: https://doi.org/10.1007/s13204-020-01516-6
M. Bhattacharya (2016) Polymer Nanocomposites-A Comparison between Carbon Nanotubes, Graphene, and Clay as Nanofillers, Materials, 9 (4), 262. https://doi.org/10.3390/ma9040262 DOI: https://doi.org/10.3390/ma9040262
M.R. Kamal, J.U. Calderon, B.R. Lennox (2009) Surface Energy of Modified Nanoclays and Its Effect on Polymer/Clay Nanocomposites, Journal of Adhesion Science and Technology, 23 (5), 663–688. https://doi.org/10.1163/156856108x379164 DOI: https://doi.org/10.1163/156856108X379164
H.S. Varol, H. Lu, N. Martzel, T. Weidner, J.E. Baio, E.H.G. Backus, D. Bonn, M.R.B. Mermet-Guyennet, M. Bonn, M.A. Sánchez, N. Encinas, S.H. Parekh, C. Malm (2015) Multiscale Effects of Interfacial Polymer Confinement in Silica Nanocomposites, Macromolecules, 48 (21), 7929–7937. https://doi.org/10.1021/acs.macromol.5b01111 DOI: https://doi.org/10.1021/acs.macromol.5b01111
Y. Liu, C. Zhang, T. Liu, Y. Wang, (2019) 2D nanosheet-constructed hybrid nanofillers for polymer nanocomposites with synergistic dispersion and function, APL Materials, 7 (8), 080904. https://doi.org/10.1063/1.5110228 DOI: https://doi.org/10.1063/1.5110228
D.G. Papageorgiou, M. Liu, R.J. Young, Z. Li, I.A. Kinloch (2020) Mechanisms of mechanical reinforcement by graphene and carbon nanotubes in polymer nanocomposites, Nanoscale, 12 (4), 2228–2267. https://doi.org/10.1039/c9nr06952f DOI: https://doi.org/10.1039/C9NR06952F
N. Bagotia, V. Choudhary, D.K. Sharma (2018) A review on the mechanical, electrical and EMI shielding properties of carbon nanotubes and graphene reinforced polycarbonate nanocomposites, Polymers for Advanced Technologies, 29 (6), 1547–1567. https://doi.org/10.1002/pat.4277 DOI: https://doi.org/10.1002/pat.4277
T. Batakliev, P.A.R. Muñoz, G.J.M. Fechine, R. Kotsilkova, E. Ivanov, V. Georgiev, C. Kalupgian, R.J.E. Andrade, V. Angelov (2021) Synergistic Effect of Graphene Nanoplatelets and Multiwall Carbon Nanotubes Incorporated in PLA Matrix: Nanoindentation of Composites with Improved Mechanical Properties, Journal of Materials Engineering and Performance, 30 (5), 3822–3830. https://doi.org/10.1007/s11665-021-05679-3 DOI: https://doi.org/10.1007/s11665-021-05679-3
D. Veeman, T. Jagadeesha, P. Sureshkumar, L. Natrayan, M. Ravichandran, P. Paramasivam, M.V. Shree (2021) Sustainable Development of Carbon Nanocomposites: Synthesis and Classification for Environmental Remediation, Journal of Nanomaterials, 2021 (1), 1–21. https://doi.org/10.1155/2021/5840645 DOI: https://doi.org/10.1155/2021/5840645
P. Song, L. Liu, C. Jin, Y. Zhang, Y. Yu, Q. Wu, Q. Li, S. Fu (2013) Striking multiple synergies created by combining reduced graphene oxides and carbon nanotubes for polymer nanocomposites, Nanotechnology, 24 (12), 125704. https://doi.org/10.1088/0957-4484/24/12/125704 DOI: https://doi.org/10.1088/0957-4484/24/12/125704
S. Santangelo, G. Gorrasi, R. Di Lieto, S. De Pasquale, G. Patimo, E. Piperopoulos, M. Lanza, G. Faggio, F. Mauriello, G. Messina, C. Milone (2010) Polylactide and carbon nanotubes/smectite-clay nanocomposites: Preparation, characterization, sorptive and electrical properties, Applied Clay Science, 53 (2), 188–194. https://doi.org/10.1016/j.clay.2010.12.013 DOI: https://doi.org/10.1016/j.clay.2010.12.013
Y. Kojima, M. Kawasumi, Y. Fukushima, T. Kurauchi, O. Kamigaito, A. Usuki, A. Okada (1993) Mechanical properties of nylon 6-clay hybrid, Journal of Materials Research, 8 (5), 1185–1189. https://doi.org/10.1557/jmr.1993.1185 DOI: https://doi.org/10.1557/JMR.1993.1185
V. Kumar, X. Tang (2023) New Horizons in Nanofiller-Based Polymer Composites II, Polymers, 15 (21), 4259. https://doi.org/10.3390/polym15214259. DOI: https://doi.org/10.3390/polym15214259
J.F. Wong, Z.B. Mohamad, A.B. Hassan, N.B. Othman, J.X. Chan (2020) Thermal and flammability properties of wollastonite-filled thermoplastic composites: a review, Journal of Materials Science, 56 (15), 8911–8950. https://doi.org/10.1007/s10853-020-05255-5 DOI: https://doi.org/10.1007/s10853-020-05255-5
P.H.M. Cardoso, M.G. De Oliveira, R.M. Da Silva Moreira Thiré, M.F.L. De Oliveira (2020) 394. 3D Printed Parts of Polylactic Acid Reinforced with Carbon Black and Alumina Nanofillers for Tribological Applications, Macromolecular Symposia, pp 2000155. https://doi.org/10.1002/masy.202000155 DOI: https://doi.org/10.1002/masy.202000155
R.N. Rothon (1999) Mineral Fillers in Thermoplastics: Filler Manufacture and Characterisation, springer berlin Heidelberg, pp 67–107. https://doi.org/10.1007/3-540-69220-7_2 DOI: https://doi.org/10.1007/3-540-69220-7_2
E. Raee, B. Kaffashi ( 2017) Biodegradable polypropylene/thermoplastic starch nanocomposites incorporating halloysite nanotubes, Journal of Applied Polymer Science, 135 (4), 45740. https://doi.org/10.1002/app.45740 DOI: https://doi.org/10.1002/app.45740
R. Rothon (2017) Particulate Fillers in Thermoset Plastics, springer, pp 111–124. https://doi.org/10.1007/978-3-319-28117-9_77 DOI: https://doi.org/10.1007/978-3-319-28117-9_77
J. Fu, J. Yuan, Q. Zhang, Y. Zhu, C. Ma (2024) Modification of Nano-α-Al2O3 and its Influence on the Surface Properties of Waterborne Polyurethane Resin Composite Passivation Films, Journal of Materials Science and Chemical Engineering, 12 (5), 29–48. https://doi.org/10.4236/msce.2024.125003 DOI: https://doi.org/10.4236/msce.2024.125003
J. Ding, Z. Huang, W. Yang, H. Luo, Y. Wang, Z. Qin, (2020) Nano-silica modified phenolic resin film: manufacturing and properties, Nanotechnology Reviews, 9 (1), 209–218. https://doi.org/10.1515/ntrev-2020-0018 DOI: https://doi.org/10.1515/ntrev-2020-0018
Y. Zhang, Y. Liu, C. Li, M. Liu, (2021) Preparation and performance study of modified silica sol/phenolic resin, BioResources, 16 (4), 6669–6683. https://doi.org/10.15376/biores.16.4.6669-6683 DOI: https://doi.org/10.15376/biores.16.4.6669-6683
S. Yeasmin, M. Murad, S.T.A. Islam, M.A. Gafur, S.S. Soshi (2022) Study of Physical, Chemical and Thermo-Mechanical Properties of Talc Filled Polyester Resin Composite Using Styrene Monomer, Materials Sciences and Applications, 13 (11), 569–585. https://doi.org/10.4236/msa.2022.1311035 DOI: https://doi.org/10.4236/msa.2022.1311035
M. Özkutlu Demirel, M.B. Öztürkmen, T. Erdem, Y. Öz, M. Savaş, E. Mutlugün (2024) Effects of silver nanowires and their surface modification on electromagnetic interference, transport and mechanical properties of an aerospace grade epoxy, Journal of Composite Materials, 58 (10), 1267–1277. https://doi.org/10.1177/00219983241238057 DOI: https://doi.org/10.1177/00219983241238057
R.V. Patel, A. Yadav, J. Winczek (2023) Physical, Mechanical, and Thermal Properties of Natural Fiber-Reinforced Epoxy Composites for Construction and Automotive Applications, Applied Sciences, 13 (8), 5126. https://doi.org/10.3390/app13085126 DOI: https://doi.org/10.3390/app13085126
A. Shundo, S. Yamamoto, K. Tanaka, (2020) Network Formation and Physical Properties of Epoxy Resins for Future Practical Applications, Journal of the American Chemical Society Au, 2 (7), 1522–1542. https://doi.org/10.1021/jacsau.2c00120 DOI: https://doi.org/10.1021/jacsau.2c00120
N. Bangsgaard, B.L. Andersen, J.P. Thyssen, A. Danielsen, N.H. Nielsen, M. Sommerlund, C.G. Mortz, E. Paulsen, G. Laurberg, B. Kristensen, J.D. Johansen, K. Kaaber, S. Vissing, N.K. Veien, C. Avnstorp, O. Kristensen, K.E. Andersen, J. Thormann, T. Menné (2012) Contact allergy to epoxy resin: risk occupations and consequences, Contact Dermatitis, 67 (2), 73–77. https://doi.org/10.1111/j.1600-0536.2012.02072.x DOI: https://doi.org/10.1111/j.1600-0536.2012.02072.x
P. Uniyal, P. Gaur, J. Yadav, N.A. Bhalla, T. Khan, H. Junaedi, T.A. Sebaey (2025) A Comprehensive Review on the Role of Nanosilica as a Toughening Agent for Enhanced Epoxy Composites for Aerospace Applications., ACS Omega, 10 (16),15810–15839. https://doi.org/10.1021/acsomega.4c10073 DOI: https://doi.org/10.1021/acsomega.4c10073
K. Kishore, K. Subbaiah (2023) Carbon Fiber and Carbon Fiber Reinforced Epoxy Composites for Automotive Applications-A Review, Journal of Advanced Research in Applied Sciences and Engineering Technology, 29(3), 272–282. https://doi.org/10.37934/araset.29.3.272282 DOI: https://doi.org/10.37934/araset.29.3.272282
M.A. Rahman, P. Farrell, B. Weclawski, M. Ndiaye (2025) Dynamic Mechanical Analysis of Borassus Husk Fiber Reinforced Epoxy: Evaluating Suitability for Advanced Aerospace and Automotive Applications, Engineering Reports, 7 (4) e70102. https://doi.org/10.1002/eng2.70102 DOI: https://doi.org/10.1002/eng2.70102
T. Haramina, N. Hadžić, Z. Keran (2023) Epoxy Resin Biocomposites Reinforced with Flax and Hemp Fibers for Marine Applications, Journal of Marine Science and Engineering, 11(2), 382. https://doi.org/10.3390/jmse11020382 DOI: https://doi.org/10.3390/jmse11020382
M.M. Rahman, M. Akhtarul Islam (2021) Application of epoxy resins in building materials: progress and prospects, Polymer Bulletin, 79 (3), 1949–1975. https://doi.org/10.1007/s00289-021-03577-1 DOI: https://doi.org/10.1007/s00289-021-03577-1
J.D. Lincoln, J.C. Earthman, A.A. Shapiro, O.A. Ogunseitan, J.-D.M. Saphores (2008) Design and Evaluation of Bioepoxy-Flax Composites for Printed Circuit Boards, IEEE Transactions on Electronics Packaging Manufacturing, 31 (3), 211–220. https://doi.org/10.1109/tepm.2008.926273 DOI: https://doi.org/10.1109/TEPM.2008.926273
Y. Meng, S.M. Tariq, H. Wu, W. Xie, H. Yang (2022) Evolution of Black Talc upon Thermal Treatment, Minerals, 12 (2), 155. https://doi.org/10.3390/min12020155 DOI: https://doi.org/10.3390/min12020155
V.E. Ogbonna, A.P.I. Popoola, O.M. Popoola (2022) A review on recent advances on the mechanical and conductivity properties of epoxy nanocomposites for industrial applications, Polymer Bulletin, 80 (2), 3449–3487. https://doi.org/10.1007/s00289-022-04249-4 DOI: https://doi.org/10.1007/s00289-022-04249-4
R. Atif, I. Shyha, F. Inam, Mechanical (2016) Thermal, and Electrical Properties of Graphene-Epoxy Nanocomposites—A Review, Polymers, 8 (8), 281. https://doi.org/10.3390/polym8080281 DOI: https://doi.org/10.3390/polym8080281
E.A. Baroncini, S. Kumar Yadav, G.R. Palmese, J.F. Stanzione (2016) Recent advances in bio‐based epoxy resins and bio‐based epoxy curing agents, Journal of Applied Polymer Science, 133 (45). https://doi.org/10.1002/app.44103. DOI: https://doi.org/10.1002/app.44103
Y. Zhang, X. Liu, M. Wan, Y. Zhu, K. Zhang (2024) Recent Development of Functional Bio-Based Epoxy Resins, Molecules, 29 (18), 4428. https://doi.org/10.3390/molecules29184428 DOI: https://doi.org/10.3390/molecules29184428
R. Kumar, A. Anand (2019) Fabrication and mechanical characterization of Indian ramie reinforced polymer composites, Materials Research Express, 6 (5), 055303. https://doi.org/10.1088/2053-1591/aaff12 DOI: https://doi.org/10.1088/2053-1591/aaff12
I. Ozsoy, H. Unal, A. Mimaroglu, Z. Demir, A. Demirkol (2015) The Influence of Micro- and Nano-Filler Content on the Mechanical Properties of Epoxy Composites, Strojniški Vestnik - Journal of Mechanical Engineering, 61, 601–609. https://doi.org/10.5545/sv-jme.2015.2632 DOI: https://doi.org/10.5545/sv-jme.2015.2632
S. Paszkiewicz, K. Walkowiak, M. Barczewski (2024) Biobased polymer nanocomposites prepared by in situ polymerization: comparison between carbon and mineral nanofillers, Journal of Materials Science, 59 (30). https://doi.org/10.1007/s10853-024-10025-8 DOI: https://doi.org/10.1007/s10853-024-10025-8
T. Gaaz, A. Al-Amiery, A. Jaaz, A. Sulong, M. Nassir, A. Kadhum (2017) The Impact of Halloysite on the Thermo-Mechanical Properties of Polymer Composites, Molecules, 22 (5), 838. https://doi.org/10.3390/molecules22050838 DOI: https://doi.org/10.3390/molecules22050838
J. Pumchusak, W. Keawsujai, P. Chaiwan, N. Thajina (2021) Effect of Organo-Modified Montmorillonite Nanoclay on Mechanical, Thermo-Mechanical, and Thermal Properties of Carbon Fiber-Reinforced Phenolic Composites, Polymers, 13 (5), 754. https://doi.org/10.3390/polym13050754 DOI: https://doi.org/10.3390/polym13050754
M. Chinnapandi, A.P. Sharma, B. Ashok Kumar Reddy, R. Velmurugan (2024) Mechanical and thermal properties of glass fiber reinforced polymer-clay nanocomposites, Journal of Physics: Conference Series, 2817 (1), 012020. https://doi.org/10.1088/1742-6596/2817/1/012020 DOI: https://doi.org/10.1088/1742-6596/2817/1/012020
K.A. Zahidah, P. Bothi Raja, M.C. Ismail, S. Kakooei (2017) Halloysite nanotubes as nanocontainer for smart coating application: A review, Progress in Organic Coatings, 111, 175–185. https://doi.org/10.1016/j.porgcoat.2017.05.018 DOI: https://doi.org/10.1016/j.porgcoat.2017.05.018
L.A. Castillo, S.E. Barbosa (2024) Polymer Nanocomposites Based on Talc, book Chemical Physics of Polymer Nanocomposites, pp 295–342. https://doi.org/10.1002/9783527837021.ch11 DOI: https://doi.org/10.1002/9783527837021.ch11
K. Espinosa, L.A. Castillo, S.E. Barbosa (2017) 18 - Polypropylene/talc nanocomposites films as low-cost barrier materials for food packaging, book Food Packaging, Elsevier, pp. 603–636. https://doi.org/10.1016/b978-0-12-804302- DOI: https://doi.org/10.1016/B978-0-12-804302-8.00018-2
I.A. Rahman, V. Padavettan (2012) Synthesis of Silica Nanoparticles by Sol‐Gel: Size‐Dependent Properties, Surface Modification, and Applications in Silica‐Polymer Nanocomposites—A Review, Journal of Nanomaterials, 2012 (1), 1–15. https://doi.org/10.1155/2012/132424 DOI: https://doi.org/10.1155/2012/132424
M. Olek, K. Kempa, S. Jurga, M. Giersig (2005) Nanomechanical Properties of Silica-Coated Multiwall Carbon Nanotubes Poly(methyl methacrylate) Composites, Langmuir, 21 (7), 3146–3152. https://doi.org/10.1021/la0470784 DOI: https://doi.org/10.1021/la0470784
K.M. Tyner, N. Sadrieh, W.H. Doub, D.E. Godar, A.M. Wokovich (2011) The state of nano‐sized titanium dioxide (TiO2) may affect sunscreen performance, International Journal of Cosmetic Science, 33 (3), 234–244. https://doi.org/10.1111/j.1468-2494.2010.00622.x DOI: https://doi.org/10.1111/j.1468-2494.2010.00622.x
S. Ramanavicius, A. Ramanavicius, A. Jagminas (2022) Gas Sensors Based on Titanium Oxides (Review), Coatings, 12 (5), 699. https://doi.org/10.3390/coatings12050699 DOI: https://doi.org/10.3390/coatings12050699
Q. Jebur, M. Habeeb, A. Hashim, Structural (2019) A.C electrical and Optical properties of (Polyvinyl alcohol–Polyethylene Oxide–Aluminum Oxide) Nanocomposites for Piezoelectric Devices, Egyptian Journal of Chemistry, 62 (2), 719-734. https://doi.org/10.21608/ejchem.2019.14847.1900 DOI: https://doi.org/10.21608/ejchem.2019.14847.1900
A. Eltaggaz, I. Deiab, I. Nouzil (2021) Machining Ti-6Al-4V Alloy Using Nano-Cutting Fluids: Investigation and Analysis, Journal of Manufacturing and Materials Processing, 5 (2), 42. https://doi.org/10.3390/jmmp5020042 DOI: https://doi.org/10.3390/jmmp5020042
S. Shankar, J.-W. Rhim (2018) Effect of Zn salts and hydrolyzing agents on the morphology and antibacterial activity of zinc oxide nanoparticles, Environmental Chemistry Letters, 17 (2), 1105–1109. https://doi.org/10.1007/s10311-018-00835-z DOI: https://doi.org/10.1007/s10311-018-00835-z
X.J. Raj (2017) Application of EIS and SECM Studies for Investigation of Anticorrosion Properties of Epoxy Coatings Containing Zinc Oxide Nanoparticles on Mild Steel in 3.5% NaCl Solution, Journal of Materials Engineering and Performance, 26 (7), 3245–3253. https://doi.org/10.1007/s11665-017-2770-z DOI: https://doi.org/10.1007/s11665-017-2770-z
Q. Dong, S. Zhang, F. Wang, T. Wang, C. Gao, Y. Ding, M. Yang, B. Wen (2011) A polycarbonate/magnesium oxide nanocomposite with high flame retardancy, Journal of Applied Polymer Science, 123 (2), 1085–1093. https://doi.org/10.1002/app.34574 DOI: https://doi.org/10.1002/app.34574
F.-P. Du, L. Yin, W. Yang, F. Zhang, C.-Y. Tang, W.-C. Law, S.-P. Liu (2015) Enhancing the Heat Transfer Efficiency in Graphene-Epoxy Nanocomposites Using a Magnesium Oxide-Graphene Hybrid Structure, ACS Applied Materials & Interfaces, 7 (26), 14397–14403. https://doi.org/10.1021/acsami.5b03196 DOI: https://doi.org/10.1021/acsami.5b03196
T. Zhang, Y. Yang, M. Zhao, Y. Weng, F. Yang, C. Zhang (2021) Improved properties of poly(butylene adipate‐co‐terephthalate)/calcium carbonate films through silane modification, Journal of Applied Polymer Science, 138 (38), 50970. https://doi.org/10.1002/app.50970 DOI: https://doi.org/10.1002/app.50970
P. Fadia, H. Dave, S. Bhagat, S. Tyagi, S. Singh, P. Panchal, S. Dang, A. Nair (2021) Calcium carbonate nano- and microparticles: synthesis methods and biological applications, 3 Biotech, 11 (11), 457, https://doi.org/10.1007/s13205-021-02995-2 DOI: https://doi.org/10.1007/s13205-021-02995-2
X. Cao, M. Chen, H. Zhang, L. Wang (2014) Preparation, characterization, and properties of modified barium sulfate nanoparticles/polyethylene nanocomposites as T‐shaped copper intrauterine devices, Journal of Applied Polymer Science, 131 (12). https://doi.org/10.1002/app.40393 DOI: https://doi.org/10.1002/app.40393
T.-Y. Yung, J.-S. Chen, P.-T. Chen, H.-M. Cheng, W.-F. Lu, Y.-C. Tzeng, K.-N. Pang, K.-C. Tsai (2022) Corrosion Resistance and Thermal Conductivity Enhancement of Reduced Graphene Oxide-BaSO4-Epoxy Composites., Polymers, 14 (15), 3144. https://doi.org/10.3390/polym14153144 DOI: https://doi.org/10.3390/polym14153144
Z. Lu, W. Dang, D. Wang, S. E, D. Ning, J. Li, F. Jia (2020) Comparative study on the mechanical and dielectric properties of aramid fibrid, mica and nanofibrillated cellulose based binary composites, Cellulose, 27 (14), 8027–8037. https://doi.org/10.1007/s10570-020-03330-3 DOI: https://doi.org/10.1007/s10570-020-03330-3
Y. Fu, Y. Wang, Z. Gao, S. Wang, C. Xiong (2018) Enhanced breakdown strength and energy storage of PVDF‐based dielectric composites by incorporating exfoliated mica nanosheets, Polymer Composites, 40 (5), 2088–2094. https://doi.org/10.1002/pc.24991 DOI: https://doi.org/10.1002/pc.24991
J.X. Chan, Z. Mohamad, A. Hassan, N. Othman, J.F. Wong (2019) Mechanical properties of wollastonite reinforced thermoplastic composites: A review, Polymer Composites, 41 (2), 395–429. c DOI: https://doi.org/10.1002/pc.25403
T. Raja, Y. Devarajan, N. Kailiappan (2024) Study on enhancing mechanical and thermal properties of carbon fiber reinforced epoxy composite through zinc oxide nanofiller, Discover Applied Sciences, 6 (11), 566. https://doi.org/10.1007/s42452-024-06270-w DOI: https://doi.org/10.1007/s42452-024-06270-w
R. Şomoghi, A. Semenescu, V. Pasăre, O.R. Chivu, D.F. Nițoi, D.F. Marcu, B. Florea (2024) The Impact of ZnO Nanofillers on the Mechanical and Anti-Corrosion Performances of Epoxy Composites, Polymers, 16 (14), 2054. https://doi.org/10.3390/polym16142054 DOI: https://doi.org/10.3390/polym16142054
R. Giménez, V. San-Miguel, J.C. Cabanelas, B. Serrano (2022) Recent Advances in MXene/Epoxy Composites: Trends and Prospects, Polymers, 14 (6), 1170. https://doi.org/10.3390/polym14061170 DOI: https://doi.org/10.3390/polym14061170
M. Megahed, M.A.A. El‐Baky, D.E. Tobbala (2020) The effect of incorporation of hybrid silica and cobalt ferrite nanofillers on the mechanical characteristics of glass fiber‐reinforced polymeric composites, Polymer Composites, 42 (1), 271–284. https://doi.org/10.1002/pc.25823 DOI: https://doi.org/10.1002/pc.25823
C. Kurtulus, M. Ciftci, M. Kuyumcu, M.A. Tasdelen (2021) Influence of POSS nanoparticles on the microstructure and mechanical properties of carbon fiber reinforced epoxy hybrid composites, Polymer Composites, 42 (8), 4056–4064. https://doi.org/10.1002/pc.26116 DOI: https://doi.org/10.1002/pc.26116
S.S. Vinay, S. Siengchin, M.R. Sanjay, C.V. Venkatesh (2020) Effect of Al2O3 nanofillers in basalt/epoxy composites: Mechanical and tribological properties, Polymer Composites, 42 (4), 1727–1740. https://doi.org/10.1002/pc.25927 DOI: https://doi.org/10.1002/pc.25927
A. Kutvonen, N.K.J. Rostedt, S.R. Puisto, T. Ala-Nissila, G. Rossi (2012) Influence of nanoparticle size, loading, and shape on the mechanical properties of polymer nanocomposites, The Journal of Chemical Physics, 137 (21), 214901. https://doi.org/10.1063/1.4767517 DOI: https://doi.org/10.1063/1.4767517
M.A. Ashraf, W. Peng, Y. Zare, K.Y. Rhee (2018), Effects of Size and Aggregation/Agglomeration of Nanoparticles on the Interfacial/Interphase Properties and Tensile Strength of Polymer Nanocomposites, Nanoscale Research Letters, 13 (1), 214. https://doi.org/10.1186/s11671-018-2624-0 DOI: https://doi.org/10.1186/s11671-018-2624-0
E. Lizundia, I. Serna, J.L. Vilas, E. Axpe (2017) Free‐volume effects on the thermomechanical performance of epoxy–SiO2 nanocomposites, Journal of Applied Polymer Science, 134 (34), 45216. https://doi.org/10.1002/app.45216 DOI: https://doi.org/10.1002/app.45216
S. Kumar, S. Baruah, A. Puzari (2019) Poly(p-phenylenediamine)-based nanocomposites with metal oxide nanoparticle for optoelectronic and magneto-optic application, Polymer Bulletin, 77 (1), 441–457. https://doi.org/10.1007/s00289-019-02760-9 DOI: https://doi.org/10.1007/s00289-019-02760-9
F. Bondioli, E. Fabbri, V. Cannillo, M. Messori (2005) Epoxy‐silica nanocomposites: Preparation, experimental characterization, and modeling, Journal of Applied Polymer Science, 97 (6), 2382–2386. https://doi.org/10.1002/app.21854 DOI: https://doi.org/10.1002/app.21854
Q. Fang, K. Lafdi (2021) Effect of nanofiller morphology on the electrical conductivity of polymer nanocomposites, Nano Express, 2 (1), 010019. https://doi.org/10.1088/2632-959x/abe13f DOI: https://doi.org/10.1088/2632-959X/abe13f
A. Baysal, G.S. Ustabasi, H. Saygin (2023) Influence of environmental media on carbon nanotubes and graphene nanoplatelets towards bacterial toxicity, Archives of Environmental Protection, 44 (3), 85-98. https://doi.org/10.24425/aep.2018.122283 DOI: https://doi.org/10.24425/aep.2018.122283
A. Kumar, K. Sharma, A.R. Dixit (2019) Carbon nanotube- and graphene-reinforced multiphase polymeric composites: review on their properties and applications, Journal of Materials Science, 55 (7), 2682–2724. https://doi.org/10.1007/s10853-019-04196-y DOI: https://doi.org/10.1007/s10853-019-04196-y
T.Y. Poh, S.H. Chotirmall, M.I. Setyawati, M.H. Kathawala, N.A.B.M. Ali, K.W. Ng, M. Mac Aogáin (2018) Inhaled nanomaterials and the respiratory microbiome: clinical, immunological and toxicological perspectives, Particle and Fibre Toxicology, 15 (1), 46. https://doi.org/10.1186/s12989-018-0282-0 DOI: https://doi.org/10.1186/s12989-018-0282-0
F.N. Ahmad, M. Jaafar, S. Palaniandy, K.A.M. Azizli (2007) Effect of particle shape of silica mineral on the properties of epoxy composites, Composites Science and Technology, 68 (2), 346–353. https://doi.org/10.1016/j.compscitech.2007.07.015 DOI: https://doi.org/10.1016/j.compscitech.2007.07.015
V. Hiremath, D.K. Shukla (2016) Effect of particle morphology on viscoelastic and flexural properties of epoxy–alumina polymer nanocomposites, Plastics, Rubber and Composites, 45 (5), 199–206. https://doi.org/10.1080/14658011.2016.1159778 DOI: https://doi.org/10.1080/14658011.2016.1159778
T. Mahrholz, J. Stängle, and M. Sinapius (2009) Quantitation of the reinforcement effect of silica nanoparticles in epoxy resins used in liquid composite moulding processes, Composites Part A: Applied Science and Manufacturing, 40 (3), 235-243, https://doi.org/10.1016/j.compositesa.2008.11.008 DOI: https://doi.org/10.1016/j.compositesa.2008.11.008
S. Deng, L. Ye, and K. Friedrich (2007) Fracture behaviours of epoxy nanocomposites with nano-silica at low and elevated temperatures, Journal of materials science, 42 (8), 2766-2774. https://doi.org/10.1007/s10853-006-1420-x DOI: https://doi.org/10.1007/s10853-006-1420-x
Y. Liu and S. Li, (2005) Using silica nanoparticles as curing reagents for epoxy resins to form epoxy–silica nanocomposites, Journal of applied polymer science, 95 (5), 1237-1245, https://doi.org/10.1002/app.21327 DOI: https://doi.org/10.1002/app.21327
https://doi.org/10.1002/pi.3183 DOI: https://doi.org/10.1002/pi.3183
S. Habib, E. Fayyed, R. A. Shakoor, R. Kahraman, and A. Abdullah (2021), Improved self-healing performance of polymeric nanocomposites reinforced with talc nanoparticles (TNPs) and urea-formaldehyde microcapsules (UFMCs), Arabian Journal of Chemistry, 14 (2), 102926. https://doi.org/10.1016/j.arabjc.2020.102926 DOI: https://doi.org/10.1016/j.arabjc.2020.102926
S. Mishra, S. Sonawane, and V. Chitodkar (2005) Comparative study on improvement in mechanical and flame retarding properties of epoxy-CaCO3 nano and commercial composites, Polymer-Plastic Technology and Engineering, 44 (3), 463-473. https://doi.org/10.1081/PTE-200048299 DOI: https://doi.org/10.1081/PTE-200048299
C. L. Poh, T. P. Chuah, C. H. Ng, C. K. Chee, M. N. Ahmad Fauzi, and M. Mariatti (2014) Tensile, dielectric, and thermal properties of epoxy composites filled with silica, mica, and calcium carbonate, Journal of Materials Science: Materials in Electronics, 25 (5), 2111-2119. https://doi.org/10.1007/s10854-014-1847-9 DOI: https://doi.org/10.1007/s10854-014-1847-9
L. Li, J. Chen, L. Shao, G. Wang, and H. Zou (2005) Study on mechanical property of epoxy composite filled with nano-sized calcium carbonate particles, Journal of materials science, 40 (5), 1297-1299. https://doi.org/10.1007/s10853-005-6956-7 DOI: https://doi.org/10.1007/s10853-005-6956-7
Q. Shi, X. Dong, L. Wang, S. Jiang, H. Yu, and Z. Zhao (2006) A novel epoxy resin/CaCO3 nanocomposite and its mechanism of toughness improvement, Macromolecular Materials and Engineering, 291 (1), 53-58. Dec. 2005, https://doi.org/10.1002/mame.200500223 DOI: https://doi.org/10.1002/mame.200500223
G. Yang, S.-J. Park, and Y.-J. Heo (2019) Effect of morphology of calcium carbonate on toughness behavior and thermal stability of epoxy-based composites, Processes, 7 (4), 178. https://doi.org/10.3390/pr7040178 DOI: https://doi.org/10.3390/pr7040178
H.-T. Huynh, K. Benzarti, and M. Duc (2012) Role of interfacial chemistry on the rheology and thermo-mechanical properties of clay-polymer nanocomposites for building applications, Chemical Papers, 66 (5) 519-53. https://doi.org/10.2478/s11696-011-0118-y DOI: https://doi.org/10.2478/s11696-011-0118-y
H. Miyagawa and L. T. Drzal (2004) The effect of chemical modification on the fracture toughness of montmorillonite clay/epoxy nanocomposites, Journal of Adhesion Science and Technology, 18 (13), 1571–1588. https://doi.org/10.1163/1568561042411204 DOI: https://doi.org/10.1163/1568561042411204
N. Guo, M. He, J. Gao, L. He, R. Meng, Y. Zhang, H. Hu (2022) Properties and Simulating Research of Epoxy Resin/Micron-SiC/Nano-SiO2 Composite, Energies, 15 (13), 4821. https://doi.org/10.3390/en15134821 DOI: https://doi.org/10.3390/en15134821
H. Li, C. Huang, Y. Liu, B. Cheng, H. Zhao, W. Gao, P. Lu, C. Feng (2022) Recent research progress and advanced applications of silica/polymer nanocomposites, Nanotechnology Reviews, 11 (1), 2928–2964. https://doi.org/10.1515/ntrev-2022-0484 DOI: https://doi.org/10.1515/ntrev-2022-0484
W. Zhou, D. Yu (2011) Effect of coupling agents on the dielectric properties of aluminum particles reinforced epoxy resin composites, Journal of Composite Materials, 45 (19), 1981–1989. https://doi.org/10.1177/0021998310394694 DOI: https://doi.org/10.1177/0021998310394694
Q.L. Ji, M.Z. Rong, B. Wetzel, K. Friedrich, M.Q. Zhang (2004) Tribological properties of surface modified nano-alumina/epoxy composites, Journal of Materials Science, 39 (21), 6487–6493. https://doi.org/10.1023/b:jmsc.0000044887.27884.1e DOI: https://doi.org/10.1023/B:JMSC.0000044887.27884.1e
C. Sciancalepore, M. Messori, F. Bondioli (2016) Non-hydrolytic sol–gel synthesis and reactive suspension method: an innovative approach to obtain magnetite–epoxy nanocomposite materials, Journal of Sol-Gel Science and Technology, 81 (1), 69–83. https://doi.org/10.1007/s10971-016-4095-z DOI: https://doi.org/10.1007/s10971-016-4095-z
S. Sprenger (2013) Fiber-reinforced composites based on epoxy resins modified with elastomers and surface-modified silica nanoparticles, Journal of Materials Science, 49 (6), 2391–2402. https://doi.org/10.1007/s10853-013-7963-8 DOI: https://doi.org/10.1007/s10853-013-7963-8
S. Suresh, P. Saravanan, K. Jayamoorthy, S. Ananda Kumar, S. Karthikeyan (2016) Development of silane grafted ZnO core shell nanoparticles loaded diglycidyl epoxy nanocomposites film for antimicrobial applications, Materials Science and Engineering: C, 64, 286–292. https://doi.org/10.1016/j.msec.2016.03.096 DOI: https://doi.org/10.1016/j.msec.2016.03.096
B. Feichtenschlager, M. Sajjad, G. Kickelbick, S. Pabisch, J. Svehla, H. Peterlik, T. Koch (2020) Epoxy Resin Nanocomposites: The Influence of Interface Modification on the Dispersion Structure—A Small-Angle-X-ray-Scattering Study, Surfaces, 3 (4), 664–682. https://doi.org/10.3390/surfaces3040044 DOI: https://doi.org/10.3390/surfaces3040044
H. He, J. Wang, J. Wang, K. Li, G. Sun, Y. Li (2011) Study on thermal and mechanical properties of nano-calcium carbonate/epoxy composites, Materials & Design, 32 (8-9), 4521–4527. https://doi.org/10.1016/j.matdes.2011.03.026 DOI: https://doi.org/10.1016/j.matdes.2011.03.026
N.H.M. Zulfli, A.A. Bakar, W.S. Chow (2013) Mechanical and thermal properties improvement of nano calcium carbonate-filled epoxy/glass fiber composite laminates, High Performance Polymers, 26 (2), 223–229. https://doi.org/10.1177/0954008313507961 DOI: https://doi.org/10.1177/0954008313507961
N. Phonthammachai, X. Li, S. Wong, H. Chia, W.W. Tjiu, C. He (2011) Fabrication of CFRP from high performance clay/epoxy nanocomposite: Preparation conditions, thermal–mechanical properties and interlaminar fracture characteristics, Composites Part A: Applied Science and Manufacturing, 42 (8), 881–887. https://doi.org/10.1016/j.compositesa.2011.02.014 DOI: https://doi.org/10.1016/j.compositesa.2011.02.014
A. Haque, F. Hussain, D. Dean, M. Shamsuzzoha (2003) S2-Glass/Epoxy Polymer Nanocomposites: Manufacturing, Structures, Thermal and Mechanical Properties, Journal of Composite Materials, 37 (20), 1821–1837. https://doi.org/10.1177/002199803035186 DOI: https://doi.org/10.1177/002199803035186
N. Sharma, V. Singal, and D. D’Melo (2013) Evaluation of water vapour permeability of solventless epoxy–nano talc/montmorrilonite amino‐silane coupled coatings, Pigment & Resin Technology, 42 (1), 45-52. https://doi.org/10.1108/03699421311288751 DOI: https://doi.org/10.1108/03699421311288751
M. Kalaee, S. Akhlaghi, A. Nouri, S. Mazinani, M. Mortezaei, M. Afshari, D. Mostafanezhad, A. Allahbakhsh, H.A. Dehaghi, A. Amirsadri, D.P. Gohari (2011) Effect of nano-sized calcium carbonate on cure kinetics and properties of polyester/epoxy blend powder coatings, Progress in Organic Coatings, 71 (2), 173–180. https://doi.org/10.1016/j.porgcoat.2011.02.006 DOI: https://doi.org/10.1016/j.porgcoat.2011.02.006
P. Rosso and L. Ye (2007) Epoxy/Silica Nanocomposites: Nanoparticle‐Induced Cure Kinetics and Microstructure, Macromolecular Rapid Communications, 28 (1), 121–126. https://doi.org/10.1002/marc.200600588 DOI: https://doi.org/10.1002/marc.200600588
H. Li, F. Liu, H. Tian, C. Wang, Z. Guo, P. Liu, Z. Peng, Q. Wang (2018) Synergetic enhancement of mechanical and electrical strength in epoxy/silica nanocomposites via chemically-bonded interface, Composites Science and Technology, 167, 539–546. https://doi.org/10.1016/j.compscitech.2018.08.047 DOI: https://doi.org/10.1016/j.compscitech.2018.08.047
A. Kamran-Pirzaman, Y. Rostamian, S. Babatabar (2020) Surface improvement effect of silica nanoparticles on epoxy nanocomposites mechanical and physical properties, and curing kinetic, Journal of Polymer Research, 27 (1), 13. https://doi.org/10.1007/s10965-019-1918-y DOI: https://doi.org/10.1007/s10965-019-1918-y
P. Luo, M. Xu, Y. Xu, and S. Wang (2017) Structural, dynamic mechanical and dielectric properties of mesoporous silica/epoxy resin nanocomposites, IEEE Transactions on Dielectrics and Electrical Insulation, 24 (3), 1685-1697. https://doi.org/10.1109/tdei.2017.006151 DOI: https://doi.org/10.1109/TDEI.2017.006151
S. Mehmood, M. Haroon, N. Ali, F. Ali, F. Haq, and S. Fahad (2021) The influence of surface modified silica nanoparticles: properties of epoxy nanocomposites, Zeitschrift Für Physikalische Chemie, 235 (5), 649-661. https://doi.org/10.1515/zpch-2019-1544 DOI: https://doi.org/10.1515/zpch-2019-1544
A. Bartolozzi, P. Sgarbossa, A. Fabrizi, E. Burigo, F. Simionato, S. Tamburini, M. Quaresimin, R. Bertani, F. Panozzo, M. Zappalorto, F. Zorzi (2017) Multifunctional Cu2+‐montmorillonite/epoxy resin nanocomposites with antibacterial activity, Journal of Applied Polymer Science, 134 (16) https://doi.org/10.1002/app.44733 DOI: https://doi.org/10.1002/app.44733
M.S. Islam, H. Rostami, R. Masoodi (2013) The Effect of Nanoparticles Percentage on Mechanical Behavior of Silica-Epoxy Nanocomposites, Journal of Nanoscience, 2013 (1), 275037. https://doi.org/10.1155/2013/275037 DOI: https://doi.org/10.1155/2013/275037
B. Ramezanzadeh, M.M. Attar, M. Farzam (2010) Effect of ZnO nanoparticles on the thermal and mechanical properties of epoxy-based nanocomposite, Journal of Thermal Analysis and Calorimetry, 103 (2), 731–739. https://doi.org/10.1007/s10973-010-0996-1 DOI: https://doi.org/10.1007/s10973-010-0996-1
R. Jain, V. Choudhary, A.K. Narula (2009) Studies on epoxy/calcium carbonate nanocomposites, Journal of Applied Polymer Science, 114 (4), 2161–2168. https://doi.org/10.1002/app.30292 DOI: https://doi.org/10.1002/app.30292
S. Shahbakhsh, E. Tohidlou, H. Khosravi (2019) Influence of modified carbonate calcium nanoparticles on the mechanical properties of carbon fiber/epoxy composites, The Journal of The Textile Institute, 111(4), 550–554. https://doi.org/10.1080/00405000.2019.1651155 DOI: https://doi.org/10.1080/00405000.2019.1651155
S.K. Singh, A. Kumar, A. Jain, D. Singh (2019) An Analysis of Mechanical and Viscoelastic Behaviour of Nano-SiO2 Dispersed Epoxy Composites, Silicon, 12 (10), 2465–2477. https://doi.org/10.1007/s12633-019-00335-x DOI: https://doi.org/10.1007/s12633-019-00335-x
M. Zappalorto, A. Pontefisso, A. Fabrizi, M. Quaresimin (2015) Mechanical behaviour of epoxy/silica nanocomposites: Experiments and modelling, Composites Part A: Applied Science and Manufacturing, 72, 58–64. https://doi.org/10.1016/j.compositesa.2015.01.027 DOI: https://doi.org/10.1016/j.compositesa.2015.01.027
B. Suresha, C. A. Varun, N. M. Indushekhara, V. Venkatesh, and H. R. Vishwanath (2019) Effect of nano filler reinforcement on mechanical properties of epoxy composites, IOP conference series: Materials science and engineering, 574 (1), p. 012010 https://doi.org/10.1088/1757-899x/574/1/012010 DOI: https://doi.org/10.1088/1757-899X/574/1/012010
S. Tiwari, C. Gehlot, and D. Srivastava (2021) Synergistic influence of CaCO3 nanoparticle on the mechanical and thermal of fly ash reinforced epoxy polymer composites, Materials Today: Proceedings, 43, 3375-3385. https://doi.org/10.1016/j.matpr.2020.06.205 DOI: https://doi.org/10.1016/j.matpr.2020.06.205
V. Eskizeybek, Ö. S. Şahin, H. B. Kaybal, A. Avcı, and H. Ulus (2018) Static and dynamic mechanical responses of CaCO3 nanoparticle modified epoxy/carbon fiber nanocomposites, Composites Part B: Engineering, 140, 223-231. https://doi.org/10.1016/j.compositesb.2017.12.013 DOI: https://doi.org/10.1016/j.compositesb.2017.12.013
F.-L. Jin and S.-J. Park (2009) Thermal stability of trifunctional epoxy resins modified with nanosized calcium carbonate, Bulletin of the Korean Chemical Society, 30 (2), 334-338. https://doi.org/10.5012/bkcs.2009.30.2.334 DOI: https://doi.org/10.5012/bkcs.2009.30.2.334
T. B. Miranda and G. G. Silva (2020) Hierarchical microstructure of nanoparticles of calcium carbonate/epoxy composites: thermomechanical and surface properties, Express Polymer Letters, 14 (2), 179-191. https://doi.org/10.3144/expresspolymlett.2020.15 DOI: https://doi.org/10.3144/expresspolymlett.2020.15
H. Shi, G. Zhang, N. Gao, H. Jin, and B. Chen (2010) Preparation and dielectric properties of epoxy/silica nanocomposites, 3rd International Nanoelectronics Conference (INEC), IEEE, pp 999–1000. https://doi.org/10.1109/inec.2010.5425080 DOI: https://doi.org/10.1109/INEC.2010.5425080
G. Ragosta, M. Abbate, P. Musto, G. Scarinzi, and L. Mascia (2005) Epoxy-silica particulate nanocomposites: chemical interactions, reinforcement and fracture toughness, Polymer, 46 (23), 10506-10516. https://doi.org/10.1016/j.polymer.2005.08.028. DOI: https://doi.org/10.1016/j.polymer.2005.08.028
Z.-Z. Wang, M. Y. M. Chiang, Z. Zhang, P. Gu, X.-P. Wu, and H. Zhang (2013) Micro/nano-wear studies on epoxy/silica nanocomposites, Composites science and technology, 79, 49-57. https://doi.org/10.1016/j.compscitech.2013.02.010 DOI: https://doi.org/10.1016/j.compscitech.2013.02.010
S. Bagheri, M. Khosravi, M. Hashemian, and A. Khandan (2020) An experimental and analytical investigation of novel nanocomposite reinforced with nanoclay with enhanced properties for low velocity impact test, Journal of Nanostructures, 10, 92-106 https://doi.org/10.22052/jns.2020.01.011
A. Chandramohan and M. Alagar (2011) Synthesis and characterization of 1, 1-bis (3-methyl-4-epoxyphenyl) cyclohexane-toughened DGEBA and TGDDM organo clay hybrid nanocomposites, High performance polymers, 23 (3), 197-211. https://doi.org/10.1177/0954008310397634 DOI: https://doi.org/10.1177/0954008310397634
P. Szymoniak, X. Qu, K. Saalwächter, C. Schick, S. Henning, D.-Y. Wang, Z. Li, B.R. Pauw, M. Abbasi, A. Schönhals (2021) Spatial inhomogeneity, interfaces and complex vitrification kinetics in a network forming nanocomposite, Soft Matter, 17 (10), 2775-2790. https://doi.org/10.1039/d0sm01992e DOI: https://doi.org/10.1039/D0SM01992E






