Enhancing epoxy nanocomposites with mineral nanofillers:A comprehensive review of particle size, shape, and concentration

Authors

DOI:

https://doi.org/10.62638/ZasMat1554

Abstract

Mineral nanofillers have emerged as promising reinforcements for epoxy nanocomposites, offering enhanced mechanical, thermal, and physical properties of the latter. This review comprehensively explores the influence of mineral nanofiller morphology, surface modification, and loading on the performance of epoxy nanocomposites. The size and shape of nanoparticles significantly affect the interfacial interactions and dispersion within the epoxy matrix, with smaller particles and higher aspect ratios generally leading to improved properties. Surface modification techniques, such as the use of coupling agents, polymer grafting, and functionalization, are crucial for optimizing the compatibility and bonding between nanofillers and epoxy matrix. The loading concentration of mineral nanofillers plays a critical role in determining the final properties of nanocomposites, with optimal loadings varying depending on the specific nanofiller and the desired enhancements. Key mineral nanofillers, including nano-silica, nano-clay, nano-calcium carbonate (CaCO3), and nano-talc, have demonstrated remarkable improvements in mechanical strength, thermal stability, and barrier properties when incorporated into epoxy matrix. This review provides valuable insights into the complex interplay between nanofiller characteristics and epoxy nanocomposite performance, guiding the design and development of advanced materials for various applications.

Keywords:

Epoxy composites, Mineral nanofillers, Particle size, Particle shape, Morphology, Surface modification, Filler Loading, Nano-silica, Nano-clay, Nano-CaCO3, Nano-Talc

References

J.J. Fekiač, M. Krbata, M. Kohutiar, R. Janík, L. Kakošová, A. Breznická, M. Eckert, P. Mikuš (2025) Comprehensive Review: Optimization of Epoxy Composites, Mechanical Properties, & Technological Trends, Polymers, 17 (3), 271. https://doi.org/10.3390/polym17030271

M. Zhang, M. Zhang, D. Jiang, Z. Guo, Z. Zhai, Z. Wu, M. Li, Z. Wu, C. Wang, T. Cheng, L. Chen (2016) Epoxy nanocomposites with carbon nanotubes and montmorillonite: Mechanical properties and electrical insulation, Journal of Composite Materials, 50 (24), 3363–3372. https://doi.org/10.1177/0021998315620000

S. Barrau, C. Lacabanne, P. Demont, A. Peigney, C. Laurent (2003) DC and AC Conductivity of Carbon Nanotubes−Polyepoxy Composites, Macromolecules, 36 (14), 5187–5194. https://doi.org/10.1021/ma021263b

A. Yahyazadeh, S. Nanda, A.K. Dalai (2024) Carbon Nanotubes: A Review of Synthesis Methods and Applications, Reactions 5 (3), 429–451. https://doi.org/10.3390/reactions5030022

A.R. Kamali (2016) Eco-friendly production of high quality low cost graphene and its application in lithium ion batteries, Green Chemistry, 18 (7),1952–1964. https://doi.org/10.1039/c5gc02455b

Q. Zhang, Y. Zhang, J. Huang, F. Wei, W. Qian (2013) The Road for Nanomaterials Industry: A Review of Carbon Nanotube Production, Post‐Treatment, and Bulk Applications for Composites and Energy Storage, Small, 9 (8), 1237–1265. https://doi.org/10.1002/smll.201203252

Y. Sato, F. Watari, K.-I. Shibata, A. Yokoyama, K. Tohji (2006) Safeness of carbon nanotubes, TANSO, 2006 (225), 364–372. https://doi.org/10.7209/tanso.2006.364

A. Zeinedini, M.M. Shokrieh (2024) Agglomeration phenomenon in graphene/polymer nanocomposites: Reasons, roles, and remedies, Applied Physics Reviews, 11 (4). https://doi.org/10.1063/5.0223785

H. Du, G.J. Weng, J. Zhang, C. Fang (2022) Modeling the evolution of graphene agglomeration and the electrical and mechanical properties of graphene/polypropylene nanocomposites, Journal of Applied Polymer Science, 140 (2), e53292. https://doi.org/10.1002/app.53292

I. Alameri, M. Oltulu (2020) Mechanical properties of polymer composites reinforced by silica-based materials of various sizes, Applied Nanoscience, 10 (11), 4087–4102. https://doi.org/10.1007/s13204-020-01516-6

M. Bhattacharya (2016) Polymer Nanocomposites-A Comparison between Carbon Nanotubes, Graphene, and Clay as Nanofillers, Materials, 9 (4), 262. https://doi.org/10.3390/ma9040262

M.R. Kamal, J.U. Calderon, B.R. Lennox (2009) Surface Energy of Modified Nanoclays and Its Effect on Polymer/Clay Nanocomposites, Journal of Adhesion Science and Technology, 23 (5), 663–688. https://doi.org/10.1163/156856108x379164

H.S. Varol, H. Lu, N. Martzel, T. Weidner, J.E. Baio, E.H.G. Backus, D. Bonn, M.R.B. Mermet-Guyennet, M. Bonn, M.A. Sánchez, N. Encinas, S.H. Parekh, C. Malm (2015) Multiscale Effects of Interfacial Polymer Confinement in Silica Nanocomposites, Macromolecules, 48 (21), 7929–7937. https://doi.org/10.1021/acs.macromol.5b01111

Y. Liu, C. Zhang, T. Liu, Y. Wang, (2019) 2D nanosheet-constructed hybrid nanofillers for polymer nanocomposites with synergistic dispersion and function, APL Materials, 7 (8), 080904. https://doi.org/10.1063/1.5110228

D.G. Papageorgiou, M. Liu, R.J. Young, Z. Li, I.A. Kinloch (2020) Mechanisms of mechanical reinforcement by graphene and carbon nanotubes in polymer nanocomposites, Nanoscale, 12 (4), 2228–2267. https://doi.org/10.1039/c9nr06952f

N. Bagotia, V. Choudhary, D.K. Sharma (2018) A review on the mechanical, electrical and EMI shielding properties of carbon nanotubes and graphene reinforced polycarbonate nanocomposites, Polymers for Advanced Technologies, 29 (6), 1547–1567. https://doi.org/10.1002/pat.4277

T. Batakliev, P.A.R. Muñoz, G.J.M. Fechine, R. Kotsilkova, E. Ivanov, V. Georgiev, C. Kalupgian, R.J.E. Andrade, V. Angelov (2021) Synergistic Effect of Graphene Nanoplatelets and Multiwall Carbon Nanotubes Incorporated in PLA Matrix: Nanoindentation of Composites with Improved Mechanical Properties, Journal of Materials Engineering and Performance, 30 (5), 3822–3830. https://doi.org/10.1007/s11665-021-05679-3

D. Veeman, T. Jagadeesha, P. Sureshkumar, L. Natrayan, M. Ravichandran, P. Paramasivam, M.V. Shree (2021) Sustainable Development of Carbon Nanocomposites: Synthesis and Classification for Environmental Remediation, Journal of Nanomaterials, 2021 (1), 1–21. https://doi.org/10.1155/2021/5840645

P. Song, L. Liu, C. Jin, Y. Zhang, Y. Yu, Q. Wu, Q. Li, S. Fu (2013) Striking multiple synergies created by combining reduced graphene oxides and carbon nanotubes for polymer nanocomposites, Nanotechnology, 24 (12), 125704. https://doi.org/10.1088/0957-4484/24/12/125704

S. Santangelo, G. Gorrasi, R. Di Lieto, S. De Pasquale, G. Patimo, E. Piperopoulos, M. Lanza, G. Faggio, F. Mauriello, G. Messina, C. Milone (2010) Polylactide and carbon nanotubes/smectite-clay nanocomposites: Preparation, characterization, sorptive and electrical properties, Applied Clay Science, 53 (2), 188–194. https://doi.org/10.1016/j.clay.2010.12.013

Y. Kojima, M. Kawasumi, Y. Fukushima, T. Kurauchi, O. Kamigaito, A. Usuki, A. Okada (1993) Mechanical properties of nylon 6-clay hybrid, Journal of Materials Research, 8 (5), 1185–1189. https://doi.org/10.1557/jmr.1993.1185

V. Kumar, X. Tang (2023) New Horizons in Nanofiller-Based Polymer Composites II, Polymers, 15 (21), 4259. https://doi.org/10.3390/polym15214259.

J.F. Wong, Z.B. Mohamad, A.B. Hassan, N.B. Othman, J.X. Chan (2020) Thermal and flammability properties of wollastonite-filled thermoplastic composites: a review, Journal of Materials Science, 56 (15), 8911–8950. https://doi.org/10.1007/s10853-020-05255-5

P.H.M. Cardoso, M.G. De Oliveira, R.M. Da Silva Moreira Thiré, M.F.L. De Oliveira (2020) 394. 3D Printed Parts of Polylactic Acid Reinforced with Carbon Black and Alumina Nanofillers for Tribological Applications, Macromolecular Symposia, pp 2000155. https://doi.org/10.1002/masy.202000155

R.N. Rothon (1999) Mineral Fillers in Thermoplastics: Filler Manufacture and Characterisation, springer berlin Heidelberg, pp 67–107. https://doi.org/10.1007/3-540-69220-7_2

E. Raee, B. Kaffashi ( 2017) Biodegradable polypropylene/thermoplastic starch nanocomposites incorporating halloysite nanotubes, Journal of Applied Polymer Science, 135 (4), 45740. https://doi.org/10.1002/app.45740

R. Rothon (2017) Particulate Fillers in Thermoset Plastics, springer, pp 111–124. https://doi.org/10.1007/978-3-319-28117-9_77

J. Fu, J. Yuan, Q. Zhang, Y. Zhu, C. Ma (2024) Modification of Nano-α-Al2O3 and its Influence on the Surface Properties of Waterborne Polyurethane Resin Composite Passivation Films, Journal of Materials Science and Chemical Engineering, 12 (5), 29–48. https://doi.org/10.4236/msce.2024.125003

J. Ding, Z. Huang, W. Yang, H. Luo, Y. Wang, Z. Qin, (2020) Nano-silica modified phenolic resin film: manufacturing and properties, Nanotechnology Reviews, 9 (1), 209–218. https://doi.org/10.1515/ntrev-2020-0018

Y. Zhang, Y. Liu, C. Li, M. Liu, (2021) Preparation and performance study of modified silica sol/phenolic resin, BioResources, 16 (4), 6669–6683. https://doi.org/10.15376/biores.16.4.6669-6683

S. Yeasmin, M. Murad, S.T.A. Islam, M.A. Gafur, S.S. Soshi (2022) Study of Physical, Chemical and Thermo-Mechanical Properties of Talc Filled Polyester Resin Composite Using Styrene Monomer, Materials Sciences and Applications, 13 (11), 569–585. https://doi.org/10.4236/msa.2022.1311035

M. Özkutlu Demirel, M.B. Öztürkmen, T. Erdem, Y. Öz, M. Savaş, E. Mutlugün (2024) Effects of silver nanowires and their surface modification on electromagnetic interference, transport and mechanical properties of an aerospace grade epoxy, Journal of Composite Materials, 58 (10), 1267–1277. https://doi.org/10.1177/00219983241238057

R.V. Patel, A. Yadav, J. Winczek (2023) Physical, Mechanical, and Thermal Properties of Natural Fiber-Reinforced Epoxy Composites for Construction and Automotive Applications, Applied Sciences, 13 (8), 5126. https://doi.org/10.3390/app13085126

A. Shundo, S. Yamamoto, K. Tanaka, (2020) Network Formation and Physical Properties of Epoxy Resins for Future Practical Applications, Journal of the American Chemical Society Au, 2 (7), 1522–1542. https://doi.org/10.1021/jacsau.2c00120

N. Bangsgaard, B.L. Andersen, J.P. Thyssen, A. Danielsen, N.H. Nielsen, M. Sommerlund, C.G. Mortz, E. Paulsen, G. Laurberg, B. Kristensen, J.D. Johansen, K. Kaaber, S. Vissing, N.K. Veien, C. Avnstorp, O. Kristensen, K.E. Andersen, J. Thormann, T. Menné (2012) Contact allergy to epoxy resin: risk occupations and consequences, Contact Dermatitis, 67 (2), 73–77. https://doi.org/10.1111/j.1600-0536.2012.02072.x

P. Uniyal, P. Gaur, J. Yadav, N.A. Bhalla, T. Khan, H. Junaedi, T.A. Sebaey (2025) A Comprehensive Review on the Role of Nanosilica as a Toughening Agent for Enhanced Epoxy Composites for Aerospace Applications., ACS Omega, 10 (16),15810–15839. https://doi.org/10.1021/acsomega.4c10073

K. Kishore, K. Subbaiah (2023) Carbon Fiber and Carbon Fiber Reinforced Epoxy Composites for Automotive Applications-A Review, Journal of Advanced Research in Applied Sciences and Engineering Technology, 29(3), 272–282. https://doi.org/10.37934/araset.29.3.272282

M.A. Rahman, P. Farrell, B. Weclawski, M. Ndiaye (2025) Dynamic Mechanical Analysis of Borassus Husk Fiber Reinforced Epoxy: Evaluating Suitability for Advanced Aerospace and Automotive Applications, Engineering Reports, 7 (4) e70102. https://doi.org/10.1002/eng2.70102

T. Haramina, N. Hadžić, Z. Keran (2023) Epoxy Resin Biocomposites Reinforced with Flax and Hemp Fibers for Marine Applications, Journal of Marine Science and Engineering, 11(2), 382. https://doi.org/10.3390/jmse11020382

M.M. Rahman, M. Akhtarul Islam (2021) Application of epoxy resins in building materials: progress and prospects, Polymer Bulletin, 79 (3), 1949–1975. https://doi.org/10.1007/s00289-021-03577-1

J.D. Lincoln, J.C. Earthman, A.A. Shapiro, O.A. Ogunseitan, J.-D.M. Saphores (2008) Design and Evaluation of Bioepoxy-Flax Composites for Printed Circuit Boards, IEEE Transactions on Electronics Packaging Manufacturing, 31 (3), 211–220. https://doi.org/10.1109/tepm.2008.926273

Y. Meng, S.M. Tariq, H. Wu, W. Xie, H. Yang (2022) Evolution of Black Talc upon Thermal Treatment, Minerals, 12 (2), 155. https://doi.org/10.3390/min12020155

V.E. Ogbonna, A.P.I. Popoola, O.M. Popoola (2022) A review on recent advances on the mechanical and conductivity properties of epoxy nanocomposites for industrial applications, Polymer Bulletin, 80 (2), 3449–3487. https://doi.org/10.1007/s00289-022-04249-4

R. Atif, I. Shyha, F. Inam, Mechanical (2016) Thermal, and Electrical Properties of Graphene-Epoxy Nanocomposites—A Review, Polymers, 8 (8), 281. https://doi.org/10.3390/polym8080281

E.A. Baroncini, S. Kumar Yadav, G.R. Palmese, J.F. Stanzione (2016) Recent advances in bio‐based epoxy resins and bio‐based epoxy curing agents, Journal of Applied Polymer Science, 133 (45). https://doi.org/10.1002/app.44103.

Y. Zhang, X. Liu, M. Wan, Y. Zhu, K. Zhang (2024) Recent Development of Functional Bio-Based Epoxy Resins, Molecules, 29 (18), 4428. https://doi.org/10.3390/molecules29184428

R. Kumar, A. Anand (2019) Fabrication and mechanical characterization of Indian ramie reinforced polymer composites, Materials Research Express, 6 (5), 055303. https://doi.org/10.1088/2053-1591/aaff12

I. Ozsoy, H. Unal, A. Mimaroglu, Z. Demir, A. Demirkol (2015) The Influence of Micro- and Nano-Filler Content on the Mechanical Properties of Epoxy Composites, Strojniški Vestnik - Journal of Mechanical Engineering, 61, 601–609. https://doi.org/10.5545/sv-jme.2015.2632

S. Paszkiewicz, K. Walkowiak, M. Barczewski (2024) Biobased polymer nanocomposites prepared by in situ polymerization: comparison between carbon and mineral nanofillers, Journal of Materials Science, 59 (30). https://doi.org/10.1007/s10853-024-10025-8

T. Gaaz, A. Al-Amiery, A. Jaaz, A. Sulong, M. Nassir, A. Kadhum (2017) The Impact of Halloysite on the Thermo-Mechanical Properties of Polymer Composites, Molecules, 22 (5), 838. https://doi.org/10.3390/molecules22050838

J. Pumchusak, W. Keawsujai, P. Chaiwan, N. Thajina (2021) Effect of Organo-Modified Montmorillonite Nanoclay on Mechanical, Thermo-Mechanical, and Thermal Properties of Carbon Fiber-Reinforced Phenolic Composites, Polymers, 13 (5), 754. https://doi.org/10.3390/polym13050754

M. Chinnapandi, A.P. Sharma, B. Ashok Kumar Reddy, R. Velmurugan (2024) Mechanical and thermal properties of glass fiber reinforced polymer-clay nanocomposites, Journal of Physics: Conference Series, 2817 (1), 012020. https://doi.org/10.1088/1742-6596/2817/1/012020

K.A. Zahidah, P. Bothi Raja, M.C. Ismail, S. Kakooei (2017) Halloysite nanotubes as nanocontainer for smart coating application: A review, Progress in Organic Coatings, 111, 175–185. https://doi.org/10.1016/j.porgcoat.2017.05.018

L.A. Castillo, S.E. Barbosa (2024) Polymer Nanocomposites Based on Talc, book Chemical Physics of Polymer Nanocomposites, pp 295–342. https://doi.org/10.1002/9783527837021.ch11

K. Espinosa, L.A. Castillo, S.E. Barbosa (2017) 18 - Polypropylene/talc nanocomposites films as low-cost barrier materials for food packaging, book Food Packaging, Elsevier, pp. 603–636. https://doi.org/10.1016/b978-0-12-804302-

I.A. Rahman, V. Padavettan (2012) Synthesis of Silica Nanoparticles by Sol‐Gel: Size‐Dependent Properties, Surface Modification, and Applications in Silica‐Polymer Nanocomposites—A Review, Journal of Nanomaterials, 2012 (1), 1–15. https://doi.org/10.1155/2012/132424

M. Olek, K. Kempa, S. Jurga, M. Giersig (2005) Nanomechanical Properties of Silica-Coated Multiwall Carbon Nanotubes Poly(methyl methacrylate) Composites, Langmuir, 21 (7), 3146–3152. https://doi.org/10.1021/la0470784

K.M. Tyner, N. Sadrieh, W.H. Doub, D.E. Godar, A.M. Wokovich (2011) The state of nano‐sized titanium dioxide (TiO2) may affect sunscreen performance, International Journal of Cosmetic Science, 33 (3), 234–244. https://doi.org/10.1111/j.1468-2494.2010.00622.x

S. Ramanavicius, A. Ramanavicius, A. Jagminas (2022) Gas Sensors Based on Titanium Oxides (Review), Coatings, 12 (5), 699. https://doi.org/10.3390/coatings12050699

Q. Jebur, M. Habeeb, A. Hashim, Structural (2019) A.C electrical and Optical properties of (Polyvinyl alcohol–Polyethylene Oxide–Aluminum Oxide) Nanocomposites for Piezoelectric Devices, Egyptian Journal of Chemistry, 62 (2), 719-734. https://doi.org/10.21608/ejchem.2019.14847.1900

A. Eltaggaz, I. Deiab, I. Nouzil (2021) Machining Ti-6Al-4V Alloy Using Nano-Cutting Fluids: Investigation and Analysis, Journal of Manufacturing and Materials Processing, 5 (2), 42. https://doi.org/10.3390/jmmp5020042

S. Shankar, J.-W. Rhim (2018) Effect of Zn salts and hydrolyzing agents on the morphology and antibacterial activity of zinc oxide nanoparticles, Environmental Chemistry Letters, 17 (2), 1105–1109. https://doi.org/10.1007/s10311-018-00835-z

X.J. Raj (2017) Application of EIS and SECM Studies for Investigation of Anticorrosion Properties of Epoxy Coatings Containing Zinc Oxide Nanoparticles on Mild Steel in 3.5% NaCl Solution, Journal of Materials Engineering and Performance, 26 (7), 3245–3253. https://doi.org/10.1007/s11665-017-2770-z

Q. Dong, S. Zhang, F. Wang, T. Wang, C. Gao, Y. Ding, M. Yang, B. Wen (2011) A polycarbonate/magnesium oxide nanocomposite with high flame retardancy, Journal of Applied Polymer Science, 123 (2), 1085–1093. https://doi.org/10.1002/app.34574

F.-P. Du, L. Yin, W. Yang, F. Zhang, C.-Y. Tang, W.-C. Law, S.-P. Liu (2015) Enhancing the Heat Transfer Efficiency in Graphene-Epoxy Nanocomposites Using a Magnesium Oxide-Graphene Hybrid Structure, ACS Applied Materials & Interfaces, 7 (26), 14397–14403. https://doi.org/10.1021/acsami.5b03196

T. Zhang, Y. Yang, M. Zhao, Y. Weng, F. Yang, C. Zhang (2021) Improved properties of poly(butylene adipate‐co‐terephthalate)/calcium carbonate films through silane modification, Journal of Applied Polymer Science, 138 (38), 50970. https://doi.org/10.1002/app.50970

P. Fadia, H. Dave, S. Bhagat, S. Tyagi, S. Singh, P. Panchal, S. Dang, A. Nair (2021) Calcium carbonate nano- and microparticles: synthesis methods and biological applications, 3 Biotech, 11 (11), 457, https://doi.org/10.1007/s13205-021-02995-2

X. Cao, M. Chen, H. Zhang, L. Wang (2014) Preparation, characterization, and properties of modified barium sulfate nanoparticles/polyethylene nanocomposites as T‐shaped copper intrauterine devices, Journal of Applied Polymer Science, 131 (12). https://doi.org/10.1002/app.40393

T.-Y. Yung, J.-S. Chen, P.-T. Chen, H.-M. Cheng, W.-F. Lu, Y.-C. Tzeng, K.-N. Pang, K.-C. Tsai (2022) Corrosion Resistance and Thermal Conductivity Enhancement of Reduced Graphene Oxide-BaSO4-Epoxy Composites., Polymers, 14 (15), 3144. https://doi.org/10.3390/polym14153144

Z. Lu, W. Dang, D. Wang, S. E, D. Ning, J. Li, F. Jia (2020) Comparative study on the mechanical and dielectric properties of aramid fibrid, mica and nanofibrillated cellulose based binary composites, Cellulose, 27 (14), 8027–8037. https://doi.org/10.1007/s10570-020-03330-3

Y. Fu, Y. Wang, Z. Gao, S. Wang, C. Xiong (2018) Enhanced breakdown strength and energy storage of PVDF‐based dielectric composites by incorporating exfoliated mica nanosheets, Polymer Composites, 40 (5), 2088–2094. https://doi.org/10.1002/pc.24991

J.X. Chan, Z. Mohamad, A. Hassan, N. Othman, J.F. Wong (2019) Mechanical properties of wollastonite reinforced thermoplastic composites: A review, Polymer Composites, 41 (2), 395–429. c

T. Raja, Y. Devarajan, N. Kailiappan (2024) Study on enhancing mechanical and thermal properties of carbon fiber reinforced epoxy composite through zinc oxide nanofiller, Discover Applied Sciences, 6 (11), 566. https://doi.org/10.1007/s42452-024-06270-w

R. Şomoghi, A. Semenescu, V. Pasăre, O.R. Chivu, D.F. Nițoi, D.F. Marcu, B. Florea (2024) The Impact of ZnO Nanofillers on the Mechanical and Anti-Corrosion Performances of Epoxy Composites, Polymers, 16 (14), 2054. https://doi.org/10.3390/polym16142054

R. Giménez, V. San-Miguel, J.C. Cabanelas, B. Serrano (2022) Recent Advances in MXene/Epoxy Composites: Trends and Prospects, Polymers, 14 (6), 1170. https://doi.org/10.3390/polym14061170

M. Megahed, M.A.A. El‐Baky, D.E. Tobbala (2020) The effect of incorporation of hybrid silica and cobalt ferrite nanofillers on the mechanical characteristics of glass fiber‐reinforced polymeric composites, Polymer Composites, 42 (1), 271–284. https://doi.org/10.1002/pc.25823

C. Kurtulus, M. Ciftci, M. Kuyumcu, M.A. Tasdelen (2021) Influence of POSS nanoparticles on the microstructure and mechanical properties of carbon fiber reinforced epoxy hybrid composites, Polymer Composites, 42 (8), 4056–4064. https://doi.org/10.1002/pc.26116

S.S. Vinay, S. Siengchin, M.R. Sanjay, C.V. Venkatesh (2020) Effect of Al2O3 nanofillers in basalt/epoxy composites: Mechanical and tribological properties, Polymer Composites, 42 (4), 1727–1740. https://doi.org/10.1002/pc.25927

A. Kutvonen, N.K.J. Rostedt, S.R. Puisto, T. Ala-Nissila, G. Rossi (2012) Influence of nanoparticle size, loading, and shape on the mechanical properties of polymer nanocomposites, The Journal of Chemical Physics, 137 (21), 214901. https://doi.org/10.1063/1.4767517

M.A. Ashraf, W. Peng, Y. Zare, K.Y. Rhee (2018), Effects of Size and Aggregation/Agglomeration of Nanoparticles on the Interfacial/Interphase Properties and Tensile Strength of Polymer Nanocomposites, Nanoscale Research Letters, 13 (1), 214. https://doi.org/10.1186/s11671-018-2624-0

E. Lizundia, I. Serna, J.L. Vilas, E. Axpe (2017) Free‐volume effects on the thermomechanical performance of epoxy–SiO2 nanocomposites, Journal of Applied Polymer Science, 134 (34), 45216. https://doi.org/10.1002/app.45216

S. Kumar, S. Baruah, A. Puzari (2019) Poly(p-phenylenediamine)-based nanocomposites with metal oxide nanoparticle for optoelectronic and magneto-optic application, Polymer Bulletin, 77 (1), 441–457. https://doi.org/10.1007/s00289-019-02760-9

F. Bondioli, E. Fabbri, V. Cannillo, M. Messori (2005) Epoxy‐silica nanocomposites: Preparation, experimental characterization, and modeling, Journal of Applied Polymer Science, 97 (6), 2382–2386. https://doi.org/10.1002/app.21854

Q. Fang, K. Lafdi (2021) Effect of nanofiller morphology on the electrical conductivity of polymer nanocomposites, Nano Express, 2 (1), 010019. https://doi.org/10.1088/2632-959x/abe13f

A. Baysal, G.S. Ustabasi, H. Saygin (2023) Influence of environmental media on carbon nanotubes and graphene nanoplatelets towards bacterial toxicity, Archives of Environmental Protection, 44 (3), 85-98. https://doi.org/10.24425/aep.2018.122283

A. Kumar, K. Sharma, A.R. Dixit (2019) Carbon nanotube- and graphene-reinforced multiphase polymeric composites: review on their properties and applications, Journal of Materials Science, 55 (7), 2682–2724. https://doi.org/10.1007/s10853-019-04196-y

T.Y. Poh, S.H. Chotirmall, M.I. Setyawati, M.H. Kathawala, N.A.B.M. Ali, K.W. Ng, M. Mac Aogáin (2018) Inhaled nanomaterials and the respiratory microbiome: clinical, immunological and toxicological perspectives, Particle and Fibre Toxicology, 15 (1), 46. https://doi.org/10.1186/s12989-018-0282-0

F.N. Ahmad, M. Jaafar, S. Palaniandy, K.A.M. Azizli (2007) Effect of particle shape of silica mineral on the properties of epoxy composites, Composites Science and Technology, 68 (2), 346–353. https://doi.org/10.1016/j.compscitech.2007.07.015

V. Hiremath, D.K. Shukla (2016) Effect of particle morphology on viscoelastic and flexural properties of epoxy–alumina polymer nanocomposites, Plastics, Rubber and Composites, 45 (5), 199–206. https://doi.org/10.1080/14658011.2016.1159778

T. Mahrholz, J. Stängle, and M. Sinapius (2009) Quantitation of the reinforcement effect of silica nanoparticles in epoxy resins used in liquid composite moulding processes, Composites Part A: Applied Science and Manufacturing, 40 (3), 235-243, https://doi.org/10.1016/j.compositesa.2008.11.008

S. Deng, L. Ye, and K. Friedrich (2007) Fracture behaviours of epoxy nanocomposites with nano-silica at low and elevated temperatures, Journal of materials science, 42 (8), 2766-2774. https://doi.org/10.1007/s10853-006-1420-x

Y. Liu and S. Li, (2005) Using silica nanoparticles as curing reagents for epoxy resins to form epoxy–silica nanocomposites, Journal of applied polymer science, 95 (5), 1237-1245, https://doi.org/10.1002/app.21327

https://doi.org/10.1002/pi.3183

S. Habib, E. Fayyed, R. A. Shakoor, R. Kahraman, and A. Abdullah (2021), Improved self-healing performance of polymeric nanocomposites reinforced with talc nanoparticles (TNPs) and urea-formaldehyde microcapsules (UFMCs), Arabian Journal of Chemistry, 14 (2), 102926. https://doi.org/10.1016/j.arabjc.2020.102926

S. Mishra, S. Sonawane, and V. Chitodkar (2005) Comparative study on improvement in mechanical and flame retarding properties of epoxy-CaCO3 nano and commercial composites, Polymer-Plastic Technology and Engineering, 44 (3), 463-473. https://doi.org/10.1081/PTE-200048299

C. L. Poh, T. P. Chuah, C. H. Ng, C. K. Chee, M. N. Ahmad Fauzi, and M. Mariatti (2014) Tensile, dielectric, and thermal properties of epoxy composites filled with silica, mica, and calcium carbonate, Journal of Materials Science: Materials in Electronics, 25 (5), 2111-2119. https://doi.org/10.1007/s10854-014-1847-9

L. Li, J. Chen, L. Shao, G. Wang, and H. Zou (2005) Study on mechanical property of epoxy composite filled with nano-sized calcium carbonate particles, Journal of materials science, 40 (5), 1297-1299. https://doi.org/10.1007/s10853-005-6956-7

Q. Shi, X. Dong, L. Wang, S. Jiang, H. Yu, and Z. Zhao (2006) A novel epoxy resin/CaCO3 nanocomposite and its mechanism of toughness improvement, Macromolecular Materials and Engineering, 291 (1), 53-58. Dec. 2005, https://doi.org/10.1002/mame.200500223

G. Yang, S.-J. Park, and Y.-J. Heo (2019) Effect of morphology of calcium carbonate on toughness behavior and thermal stability of epoxy-based composites, Processes, 7 (4), 178. https://doi.org/10.3390/pr7040178

H.-T. Huynh, K. Benzarti, and M. Duc (2012) Role of interfacial chemistry on the rheology and thermo-mechanical properties of clay-polymer nanocomposites for building applications, Chemical Papers, 66 (5) 519-53. https://doi.org/10.2478/s11696-011-0118-y

H. Miyagawa and L. T. Drzal (2004) The effect of chemical modification on the fracture toughness of montmorillonite clay/epoxy nanocomposites, Journal of Adhesion Science and Technology, 18 (13), 1571–1588. https://doi.org/10.1163/1568561042411204

N. Guo, M. He, J. Gao, L. He, R. Meng, Y. Zhang, H. Hu (2022) Properties and Simulating Research of Epoxy Resin/Micron-SiC/Nano-SiO2 Composite, Energies, 15 (13), 4821. https://doi.org/10.3390/en15134821

H. Li, C. Huang, Y. Liu, B. Cheng, H. Zhao, W. Gao, P. Lu, C. Feng (2022) Recent research progress and advanced applications of silica/polymer nanocomposites, Nanotechnology Reviews, 11 (1), 2928–2964. https://doi.org/10.1515/ntrev-2022-0484

W. Zhou, D. Yu (2011) Effect of coupling agents on the dielectric properties of aluminum particles reinforced epoxy resin composites, Journal of Composite Materials, 45 (19), 1981–1989. https://doi.org/10.1177/0021998310394694

Q.L. Ji, M.Z. Rong, B. Wetzel, K. Friedrich, M.Q. Zhang (2004) Tribological properties of surface modified nano-alumina/epoxy composites, Journal of Materials Science, 39 (21), 6487–6493. https://doi.org/10.1023/b:jmsc.0000044887.27884.1e

C. Sciancalepore, M. Messori, F. Bondioli (2016) Non-hydrolytic sol–gel synthesis and reactive suspension method: an innovative approach to obtain magnetite–epoxy nanocomposite materials, Journal of Sol-Gel Science and Technology, 81 (1), 69–83. https://doi.org/10.1007/s10971-016-4095-z

S. Sprenger (2013) Fiber-reinforced composites based on epoxy resins modified with elastomers and surface-modified silica nanoparticles, Journal of Materials Science, 49 (6), 2391–2402. https://doi.org/10.1007/s10853-013-7963-8

S. Suresh, P. Saravanan, K. Jayamoorthy, S. Ananda Kumar, S. Karthikeyan (2016) Development of silane grafted ZnO core shell nanoparticles loaded diglycidyl epoxy nanocomposites film for antimicrobial applications, Materials Science and Engineering: C, 64, 286–292. https://doi.org/10.1016/j.msec.2016.03.096

B. Feichtenschlager, M. Sajjad, G. Kickelbick, S. Pabisch, J. Svehla, H. Peterlik, T. Koch (2020) Epoxy Resin Nanocomposites: The Influence of Interface Modification on the Dispersion Structure—A Small-Angle-X-ray-Scattering Study, Surfaces, 3 (4), 664–682. https://doi.org/10.3390/surfaces3040044

H. He, J. Wang, J. Wang, K. Li, G. Sun, Y. Li (2011) Study on thermal and mechanical properties of nano-calcium carbonate/epoxy composites, Materials & Design, 32 (8-9), 4521–4527. https://doi.org/10.1016/j.matdes.2011.03.026

N.H.M. Zulfli, A.A. Bakar, W.S. Chow (2013) Mechanical and thermal properties improvement of nano calcium carbonate-filled epoxy/glass fiber composite laminates, High Performance Polymers, 26 (2), 223–229. https://doi.org/10.1177/0954008313507961

N. Phonthammachai, X. Li, S. Wong, H. Chia, W.W. Tjiu, C. He (2011) Fabrication of CFRP from high performance clay/epoxy nanocomposite: Preparation conditions, thermal–mechanical properties and interlaminar fracture characteristics, Composites Part A: Applied Science and Manufacturing, 42 (8), 881–887. https://doi.org/10.1016/j.compositesa.2011.02.014

A. Haque, F. Hussain, D. Dean, M. Shamsuzzoha (2003) S2-Glass/Epoxy Polymer Nanocomposites: Manufacturing, Structures, Thermal and Mechanical Properties, Journal of Composite Materials, 37 (20), 1821–1837. https://doi.org/10.1177/002199803035186

N. Sharma, V. Singal, and D. D’Melo (2013) Evaluation of water vapour permeability of solventless epoxy–nano talc/montmorrilonite amino‐silane coupled coatings, Pigment & Resin Technology, 42 (1), 45-52. https://doi.org/10.1108/03699421311288751

M. Kalaee, S. Akhlaghi, A. Nouri, S. Mazinani, M. Mortezaei, M. Afshari, D. Mostafanezhad, A. Allahbakhsh, H.A. Dehaghi, A. Amirsadri, D.P. Gohari (2011) Effect of nano-sized calcium carbonate on cure kinetics and properties of polyester/epoxy blend powder coatings, Progress in Organic Coatings, 71 (2), 173–180. https://doi.org/10.1016/j.porgcoat.2011.02.006

P. Rosso and L. Ye (2007) Epoxy/Silica Nanocomposites: Nanoparticle‐Induced Cure Kinetics and Microstructure, Macromolecular Rapid Communications, 28 (1), 121–126. https://doi.org/10.1002/marc.200600588

H. Li, F. Liu, H. Tian, C. Wang, Z. Guo, P. Liu, Z. Peng, Q. Wang (2018) Synergetic enhancement of mechanical and electrical strength in epoxy/silica nanocomposites via chemically-bonded interface, Composites Science and Technology, 167, 539–546. https://doi.org/10.1016/j.compscitech.2018.08.047

A. Kamran-Pirzaman, Y. Rostamian, S. Babatabar (2020) Surface improvement effect of silica nanoparticles on epoxy nanocomposites mechanical and physical properties, and curing kinetic, Journal of Polymer Research, 27 (1), 13. https://doi.org/10.1007/s10965-019-1918-y

P. Luo, M. Xu, Y. Xu, and S. Wang (2017) Structural, dynamic mechanical and dielectric properties of mesoporous silica/epoxy resin nanocomposites, IEEE Transactions on Dielectrics and Electrical Insulation, 24 (3), 1685-1697. https://doi.org/10.1109/tdei.2017.006151

S. Mehmood, M. Haroon, N. Ali, F. Ali, F. Haq, and S. Fahad (2021) The influence of surface modified silica nanoparticles: properties of epoxy nanocomposites, Zeitschrift Für Physikalische Chemie, 235 (5), 649-661. https://doi.org/10.1515/zpch-2019-1544

A. Bartolozzi, P. Sgarbossa, A. Fabrizi, E. Burigo, F. Simionato, S. Tamburini, M. Quaresimin, R. Bertani, F. Panozzo, M. Zappalorto, F. Zorzi (2017) Multifunctional Cu2+‐montmorillonite/epoxy resin nanocomposites with antibacterial activity, Journal of Applied Polymer Science, 134 (16) https://doi.org/10.1002/app.44733

M.S. Islam, H. Rostami, R. Masoodi (2013) The Effect of Nanoparticles Percentage on Mechanical Behavior of Silica-Epoxy Nanocomposites, Journal of Nanoscience, 2013 (1), 275037. https://doi.org/10.1155/2013/275037

B. Ramezanzadeh, M.M. Attar, M. Farzam (2010) Effect of ZnO nanoparticles on the thermal and mechanical properties of epoxy-based nanocomposite, Journal of Thermal Analysis and Calorimetry, 103 (2), 731–739. https://doi.org/10.1007/s10973-010-0996-1

R. Jain, V. Choudhary, A.K. Narula (2009) Studies on epoxy/calcium carbonate nanocomposites, Journal of Applied Polymer Science, 114 (4), 2161–2168. https://doi.org/10.1002/app.30292

S. Shahbakhsh, E. Tohidlou, H. Khosravi (2019) Influence of modified carbonate calcium nanoparticles on the mechanical properties of carbon fiber/epoxy composites, The Journal of The Textile Institute, 111(4), 550–554. https://doi.org/10.1080/00405000.2019.1651155

S.K. Singh, A. Kumar, A. Jain, D. Singh (2019) An Analysis of Mechanical and Viscoelastic Behaviour of Nano-SiO2 Dispersed Epoxy Composites, Silicon, 12 (10), 2465–2477. https://doi.org/10.1007/s12633-019-00335-x

M. Zappalorto, A. Pontefisso, A. Fabrizi, M. Quaresimin (2015) Mechanical behaviour of epoxy/silica nanocomposites: Experiments and modelling, Composites Part A: Applied Science and Manufacturing, 72, 58–64. https://doi.org/10.1016/j.compositesa.2015.01.027

B. Suresha, C. A. Varun, N. M. Indushekhara, V. Venkatesh, and H. R. Vishwanath (2019) Effect of nano filler reinforcement on mechanical properties of epoxy composites, IOP conference series: Materials science and engineering, 574 (1), p. 012010 https://doi.org/10.1088/1757-899x/574/1/012010

S. Tiwari, C. Gehlot, and D. Srivastava (2021) Synergistic influence of CaCO3 nanoparticle on the mechanical and thermal of fly ash reinforced epoxy polymer composites, Materials Today: Proceedings, 43, 3375-3385. https://doi.org/10.1016/j.matpr.2020.06.205

V. Eskizeybek, Ö. S. Şahin, H. B. Kaybal, A. Avcı, and H. Ulus (2018) Static and dynamic mechanical responses of CaCO3 nanoparticle modified epoxy/carbon fiber nanocomposites, Composites Part B: Engineering, 140, 223-231. https://doi.org/10.1016/j.compositesb.2017.12.013

F.-L. Jin and S.-J. Park (2009) Thermal stability of trifunctional epoxy resins modified with nanosized calcium carbonate, Bulletin of the Korean Chemical Society, 30 (2), 334-338. https://doi.org/10.5012/bkcs.2009.30.2.334

T. B. Miranda and G. G. Silva (2020) Hierarchical microstructure of nanoparticles of calcium carbonate/epoxy composites: thermomechanical and surface properties, Express Polymer Letters, 14 (2), 179-191. https://doi.org/10.3144/expresspolymlett.2020.15

H. Shi, G. Zhang, N. Gao, H. Jin, and B. Chen (2010) Preparation and dielectric properties of epoxy/silica nanocomposites, 3rd International Nanoelectronics Conference (INEC), IEEE, pp 999–1000. https://doi.org/10.1109/inec.2010.5425080

G. Ragosta, M. Abbate, P. Musto, G. Scarinzi, and L. Mascia (2005) Epoxy-silica particulate nanocomposites: chemical interactions, reinforcement and fracture toughness, Polymer, 46 (23), 10506-10516. https://doi.org/10.1016/j.polymer.2005.08.028.

Z.-Z. Wang, M. Y. M. Chiang, Z. Zhang, P. Gu, X.-P. Wu, and H. Zhang (2013) Micro/nano-wear studies on epoxy/silica nanocomposites, Composites science and technology, 79, 49-57. https://doi.org/10.1016/j.compscitech.2013.02.010

S. Bagheri, M. Khosravi, M. Hashemian, and A. Khandan (2020) An experimental and analytical investigation of novel nanocomposite reinforced with nanoclay with enhanced properties for low velocity impact test, Journal of Nanostructures, 10, 92-106 https://doi.org/10.22052/jns.2020.01.011

A. Chandramohan and M. Alagar (2011) Synthesis and characterization of 1, 1-bis (3-methyl-4-epoxyphenyl) cyclohexane-toughened DGEBA and TGDDM organo clay hybrid nanocomposites, High performance polymers, 23 (3), 197-211. https://doi.org/10.1177/0954008310397634

P. Szymoniak, X. Qu, K. Saalwächter, C. Schick, S. Henning, D.-Y. Wang, Z. Li, B.R. Pauw, M. Abbasi, A. Schönhals (2021) Spatial inhomogeneity, interfaces and complex vitrification kinetics in a network forming nanocomposite, Soft Matter, 17 (10), 2775-2790. https://doi.org/10.1039/d0sm01992e

Downloads

Published

06-03-2026

Issue

Section

Review Paper