Poly (vinylidene fluoride) polymer electrolyte-based supercapacitors

Authors

  • Fatima Ahmad Muhammad Sharda School of Engineering & Science, Department of Physics & Environmental Sciences, Sharda University, Greater Noida, India Author
  • Yashika Bajaj Sharda School of Engineering & Science, Department of Physics & Environmental Sciences, Sharda University, Greater Noida, India Author https://orcid.org/0009-0004-0334-6426
  • Ikhwan Mohd Noo Department of Chemical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur, Malaysia Author https://orcid.org/0000-0003-0983-782X
  • Muhd Zu Azhan Yahya Faculty of Defence Science and Technology, Universiti Petrahanan Nasional Malaysia (UPNM), Kuala Lumpur, Malaysia Author https://orcid.org/0000-0003-1129-0552
  • Tarun Yadav Department of Basic Sciences, IITM, IES University, Bhopal, Madhya Pradesh, India Author
  • Rohit Kumar Sharda School of Engineering & Science, Department of Physics & Environmental Sciences, Sharda University, Greater Noida, India Author
  • Pramod K. Singh Sharda School of Engineering & Science, Department of Physics & Environmental Sciences, Sharda University, Greater Noida, India Author https://orcid.org/0000-0002-3155-6621

DOI:

https://doi.org/10.62638/ZasMat1096

Abstract

PVDF, or polyvinylidenefluoride, is a popular polymer in the fluoropolymer family because of its superior mechanical strength, thermal stability, and piezoelectric qualities. It is chemically resistant to various substances, including diverse acids, bases, organic solvents, oil, and fat, and it is also easily processed. Electrochemical devices with superior energy storage effectiveness are necessary because of the increasing electricity consumption in the modern world. Because of its great power density, extended lifespan, remarkable charge/discharge cycle stability, and inexpensive cost, supercapacitors are regarded as amazing energy-storing devices. Supercapacitors' electrochemical performance is entirely dependent on the selection of their basic components and their manufacturing process. Materials made from carbon with improved thermophysical characteristics and deformation strength are currently of great interest. These materials have various applications in numerous sectors due to their distinctive physical and chemical properties. The abundance of research on the "structure-property," manufacturing, application, and ecology of composite polymers based on polyvinylidene fluoride (PVDF) can be attributed to the many opportunities for their use in science and technology. It is feasible to achieve a high degree of multidisciplinarity and integration of polymer science by using innovative technologies to build an expanded conceptual picture regarding polymeric materials. This leads to the formation of fundamental problems in polymer science, the solution of which affects a significant improvement to the natural scientific picture of the modern world.PVDF is arguably the most sought-after polymer nowadays due to its ability to self-polarize in the presence of an electric field. Researchers and experts involved in the development of energy harvesting and storage devices such as self-charging supercapacitors are drawn to the piezoelectric, ferroelectric, and pyroelectric capabilities of PVDF. The advanced properties of PVDF and its potential applications in various polymer forms are explained.

Keywords:

charge carriers, polyvinyldiene fluoride, structural properties
Supporting Agencies
Sharda university

References

R. Dallaev, T. Pisarenko, D. Sobola, F. Orudzhev, S. Ramazanov, T. Trčka (2022) Brief Review of PVDF Properties and Applications Potential, Polymers, 14(22),4793,

https://doi.org/10.3390/polym14224793

A. González, E. Goikolea, J. A. Barrena, R. Mysyk (2016) Review on supercapacitors: Technologies and materials," Renewable and Sustainable Energy Reviews, 58,1189-1206,

https://doi.org/10.1016/j.rser.2015.12.249

W. K. Chee, H. N. Lim, Z. Zainal, N. M. Huang, I. Harrison, Y. Andou (2016) Flexible Graphene-Based Supercapacitors: A Review," J. Phys. Chem. C, 120(8),4153-4172,

https://doi.org/10.1021/acs.jpcc.5b10187

V. V. Uchaikin, R. T. Sibatov, S. A. Ambrozevich (2016) Comment on 'Review of characterization methods for supercapacitor modelling,'" Journal of Power Sources, 307,112-113,

https://doi.org/10.1016/j.jpowsour.2015.12.051

Y. Luo, Q. Zhang, W. Hong, Z. Xiao, H. Bai (2018) "A high-performance electrochemical super capacitor based on a polyaniline/reduced graphene oxide electrode and a copper( II ) ion active electrolyte, Phys. Chem. Chem. Phys., 20(1),131-136,

https://doi.org/10.1039/C7CP07156F

H. Zhang, Z. Hu, M. Li, L. Hu, S.Jiao (2014) A high-performance supercapacitor based on a polythiophene/multiwalled carbon nanotube composite by electropolymerization in an ionic liquid microemulsion," J. Mater. Chem. A, 2(40), 17024-17030,

https://doi.org/10.1039/C4TA03369H

L.-Z. Fan, J.Maier (2006) "High-performance polypyrrole electrode materials for redox supercapacitors,"Electrochemistry Communications, 8(6), 937-940,

https://doi.org/10.1016/j.elecom.2006.03.035

A. Kausar (2017) "Overview on conducting polymer in energy storage and energy conversion system," Journal of Macromolecular Science, Part A, 54(9), 640-653,

https://doi.org/10.1080/10601325.2017.1317210

S. Rajeevan, S. John, S. C. George (2021) "Polyvinylidene fluoride: A multifunctional polymer in supercapacitor applications," Journal of Power Sources,504,230037,

https://doi.org/10.1016/j.jpowsour.2021.230037

Y. Wang, J. Cui, Q. Yuan, Y. Niu, Y. Bai, H. Wang (2015) "Significantly Enhanced Breakdown Strength and Energy Density in Sandwich‐Structured Barium Titanate/Poly(vinylidene fluoride) Nanocomposites," Advanced Materials, 27(42), 6658-6663,

https://doi.org/10.1002/adma.201503186

L.Priya,J. P.Jog (2003) "Intercalated poly(vinylidene fluoride)/clay nanocomposites: Structure and properties, J Polym Sci B Polym Phys, 41(1), 31-38,

https://doi.org/10.1002/polb.10355

Q.-K.Feng et al. (2022) Recent Progress and Future Prospects on All-Organic Polymer Dielectrics for Energy Storage Capacitors," Chem. Rev., 122(3), 3820-3878,

https://doi.org/10.1021/acs.chemrev.1c00793

B. B. Damdinov (2021) "Rheological Properties of PVDF Solutions," Journal of Siberian Federal University. Mathematics & Physics,4(3),265-272,

https://doi.org/10.17516/1997-1397-2021-14-3-265-272

Q. Xie, X. Huang, Y. Zhang, S. Wu, P. Zhao (2018) "High performance aqueous symmetric super-capacitors based on advanced carbon electrodes and hydrophilic poly(vinylidene fluoride) porous separator," Applied Surface Science, 443, 412-420,

https://doi.org/10.1016/j.apsusc.2018.02.274

N. Momenzadeh, H. Miyanaji, D. A. Porter, T. A. Berfield (2020) "Polyvinylidene fluoride (PVDF) as a feedstock for material extrusion additive manufacturing,RPJ, 26(1),156-163,

https://doi.org/10.1108/RPJ-08-2018-0203

I. Y. Abdullah, M. Yahaya, M. H. H. Jumali, H. M. Shanshool (2014) Effect of annealing process on the phase formation in poly(vinylidene fluoride) thin films," presented at the THE 2014 UKM FST POSTGRADUATE COLLOQUIUM: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium, Selangor, Malaysia, p.147-151.https://doi.org/10.1063/1.4895187

L. Ruan, X. Yao, Y. Chang, L. Zhou, G. Qin, X. Zhang (2018) "Properties and Applications of the β Phase Poly(vinylidene fluoride)," Polymers, 10(3), 228,

https://doi.org/10.3390/polym10030228

J. Y. Lim, S. Kim, Y. Seo (2015) "Enhancement of β-phase in PVDF by electrospinning," presented at the Proceedings of PPS-30: The 30th International Conference of the Polymer Processing Society - Conference Papers, Cleveland, Ohio, USA,: 070006.

https://doi.org/10.1063/1.4918441

A. Gebrekrstos, G. Madras, S. Bose (2019) "Journey of Electroactive β-Polymorph of Poly(vinylidenefluoride) from Crystal Growth to Design to Applications," Crystal Growth & Design, 19(9),5441-5456,

https://doi.org/10.1021/acs.cgd.9b00381

P. Sajkiewicz, A. Wasiak, Z. Gocłowski (1999) "Phase transitions during stretching of poly(vinylidene fluoride)," European Polymer Journal, 35(3), 423-429,

https://doi.org/10.1016/S0014-3057(98)00136-0

M. Khajehpour (2014) "Nanofiller Modification and Incorporation into Fluoropolymer Nanocomposites and the Properties thereof, dr. THESIS,

https://doi.org/10.11575/PRISM/27053

A. J. Lovinger (1982) "Poly(Vinylidene Fluoride)," in Developments in Crystalline Polymers-1, D. C. Bassett, Ed., Dordrecht: Springer Netherlands, p.195-273.

https://doi.org/10.1007/978-94-009-7343-5_5

S. Abbrent, J. Plestil, D. Hlavata, J. Lindgren, J. Tegenfeldt, Å. Wendsjö (2001) "Crystallinity and morphology of PVdF-HFP-based gel electrolytes," Polymer,42(4),1407-1416,

https://doi.org/10.1016/S0032-3861(00)00517-6

A. J. Lovinger (1982) "Annealing of poly(vinylidene fluoride) and formation of a fifth phase," Macromolecules, 15(1), 40-44,

https://doi.org/10.1021/ma00229a008

T. Wu et al. (2020) "A Flexible Film Bulk Acoustic Resonator Based on β-Phase Polyvinylidene Fluoride Polymer," Sensors, 20(5), 1346,

https://doi.org/10.3390/s20051346

D. K. Das-Gupta (1981) "On the nature of pyroelectricity in polyvinylidene fluoride," Ferroelectrics, 33(1),75-89,

https://doi.org/10.1080/00150198108008072

J. E. Dohany (2000) Fluorine‐Containing Polymers, Poly(Vinylidene Fluoride), in Kirk-Othmer Encyclopedia of Chemical Technology, 1st ed., Kirk-Othmer, Ed., Wiley.

https://doi.org/10.1002/0471238961.1615122504150801.a01

P. Saxena,P. Shukla (2021) A comprehensive review on fundamental properties and applications of poly(vinylidene fluoride) (PVDF)," Adv Compos Hybrid Mater,4(1), 8-26,

https://doi.org/10.1007/s42114-021-00217-0

R. Gregorio, E. M. Ueno (1999) "Effect of crystalline phase, orientation and temperature on the dielectric properties of poly (vinylidene fluoride) (PVDF)," Journal of Materials Science, 34(18), 4489-4500,

https://doi.org/10.1023/A:1004689205706

W.Eisenmenger, H.Schmidt, B.Dehlen (1999) Space charge and dipoles in polyvinylidenefluoride, Braz. J. Phys., 29(2),65-73.

https://doi.org/10.1590/S0103-97331999000200011

Y. Wei et al. (2016) A flexible, highly conductive, tough ionogel electrolyte containing LiTFSI salt and ionic liquid [EMIM][TFSI] based on PVDF-HFP for high-performance supercapacitors," Polymer, 289,126501,

https://doi.org/10.1016/j.polymer.2023.126501

P.F.R.Ortega, J.P.Trigueiro, G.G.Silva, R.L. Lavall (2016) "Improving supercapacitor capacitance by using a novel gel nanocomposite polymer electrolyte based on nanostructured SiO2, PVDF and imidazolium ionic liquid," Electrochimica Acta, 188,809-817,

https://doi.org/10.1016/j.electacta.2015.12.056

L. Yang, J. Hu, G. Lei, H. Liu (2014) "Ionic liquid-gelled polyvinylidene fluoride/polyvinyl acetate polymer electrolyte for solid supercapacitor," Chemical Engineering Journal, 258, 320-326,

https://doi.org/10.1016/j.cej.2014.05.149

M.Ahmed, G.Tatrari, P.Johansson, F.U.Shah (2024) "Sweet Ionic Liquids as High-Temperature and High-Voltage Supercapacitor Electrolytes," ACS Sustainable Chem. Eng., 12(46),16896-16904,

https://doi.org/10.1021/acssuschemeng.4c06290

F. C. A. Silva, P. F. R. Ortega, R. A. Dos Reis, R. L. Lavall, L. T. Costa (2022) "Polymer-ion interactions in PVDF@ionic liquid polymer electrolytes: A combined experimental and computational study," Electrochimica Acta, 427,140831,

https://doi.org/10.1016/j.electacta.2022.140831

R. Rathika,S. Austin Suthanthiraraj (2019) "Effect of ionic liquid 1-ethyl-3-methylimidazolium hydrogen sulfate on zinc-ion dynamics in PEO/PVdF blend gel polymer electrolytes," Ionics, 25(3),1137-1146,

https://doi.org/10.1007/s11581-018-2709-x

G. A. Dos Santos Junior, V. D. S. Fortunato, G. G. Silva, P. F. R. Ortega, R. L. Lavall (2019) "High-performance Li-Ion hybrid supercapacitor based on LiMn2O4 in ionic liquid electrolyte," Electrochimica Acta, 325,134900,

https://doi.org/10.1016/j.electacta.2019.134900

R.Nadimicherla, M.Chandra Sekhar, V.Madhu Mohan, W.Chen (2024) Poly(ethylene glycol)/ poly(vinylidene) fluoride/TiO2 nanoparticle composite for sandwiched solid-state dye-sensitized solar cells,J Mater Sci: Mater Electron, 35(15),1013

https://doi.org/10.1007/s10854-024-12731-0

P. K. Singh, B. Bhattacharya, R. K. Nagarale, K.-W. Kim, H.-W. Rhee (2010) Synthesis, characterization and application of biopolymer-ionic liquid composite membranes," Synthetic Metals,160( 1-2), 139-142,

https://doi.org/10.1016/j.synthmet.2009.10.021

Y. Shi, X. Zhou, G. Yu (2017) "Material and Structural Design of Novel Binder Systems for High-Energy, High-Power Lithium-Ion Batteries," Acc. Chem. Res., 50(11), 2642-2652,

https://doi.org/10.1021/acs.accounts.7b00402

S. Parulekar, S. Sholapure R, M. Holmukhe, P. B. Karandikar (2018) Study of PVDF Based Electrode Structure in Supercapacitors," IJET, 7( 4.5), 313,

https://doi.org/10.14419/ijet.v7i4.5.20096

D. Kalpana, N. G. Renganathan, S. Pitchumani (2016) "A new class of alkaline polymer gel electrolyte for carbon aerogel supercapacitors," Journal of Power Sources,157(1),621-623,

https://doi.org/10.1016/j.jpowsour.2005.07.057

T. Winie, A. K. Arof, S. Thomas (2020) "Polymer Electrolytes: Characterization Techniques and Energy Applications", 1st ed. Wiley,

https://doi.org/10.1002/9783527805457

E. Bekaert, L. Buannic, U. Lassi, A. Llordés, J. Salminen (2017) "Electrolytes for Li- and Na-Ion Batteries: Concepts, Candidates, and the Role of Nanotechnology," in Emerging Nanotechnologies in Rechargeable Energy Storage Systems, Elsevier, p.1-43.

https://doi.org/10.1016/B978-0-323-42977-1.00001-7

R. Kumar,S. S. Sekhon (2008) "Effect of molecular weight of PMMA on the conductivity and viscosity behavior of polymer gel electrolytes containing NH4CF3SO3," Ionics, 14(6),509-514,

https://doi.org/10.1007/s11581-008-0209-0

K. V. G. Raghavendra et al. (2020) An intuitive review of supercapacitors with recent progress and novel device applications," Journal of Energy Storage, 31,101652,

https://doi.org/10.1016/j.est.2020.101652

Downloads

Published

25-06-2025

Issue

Section

Review Paper