Tuning low frequency dielectric properties of flexible ternary polymer blend film reinforced with bio- ionic liquid for the application in green electronics
DOI:
https://doi.org/10.62638/ZasMat1001Keywords:
Bio ionic liquid, choline acetate, polyvinylchloride, polyvinylpyrrolidone, polypyrroleAbstract
Biofriendly conducting polymeric blends and composites exhibiting high dielectric constant and dielectric loss are promising for applications as sensors, actuators, microwave absorbing materials, fuel cells and biomedical applications. A great deal of work is reported on using fillers such as conductive nanomaterials, bio ceramics, carbon nanotubes, graphene etc in blends of Polyvinylchloride, Polyvinylpyrrolidone, Polymethylmethacrylate, Polyvinyl alcohol with conducting polymer Polypyrrole, Polyaniline for enhancing their conductivities, tailoring dielectric and electrical, thermal and surface properties of such polymeric materials. However, appropriate dispersion of such fillers in polymeric matrices remains technically challenging. In this regard, bio-ionic liquids have emerged as a novel class of materials and their combination with specific polymer blends opens the possibility to develop smart novel materials with different morphologies. Present work aims to explore the low frequency dielectric properties exhibited by free standing, flexible, biofriendly/biodegradable ternary polymer blend film of Polyvinylchloride-Polyvinylpyrrolidone-Polypyrrole reinforced with choline acetate. The detailed analysis of low frequency dielectric properties authenticates that addition of choline acetate result in modifying the dielectric properties of ternary polymer blend film.. The harmlessness of these films was confirmed from disk diffusion test indicating their benign nature towards (Escherichia coli) (CFT073) and (Bacillus subtilis). Therefore, the developed films can potentially be used for various scale multifunctional dielectric and electrical applications working in close contact with living matter, green electronics and various health monitoring systems.
References
A.F.Ahmad et al. (2020) Biodegradable Poly (lactic acid)/Poly (ethylene glycol) Reinforced Multi-Walled Carbon Nanotube Nanocomposite Fabrication, Characterization, Properties, and Applications, Polymers, 12, 427-449.
https://doi.org/10.3390/polym12020427
F.Elhi et al. (2020) Electromechanically active polymer actuators based on biofriendly choline ionic liquids, Smart Mater. Struct. 29, 055021.
https://doi.org/10.1088/1361-665X/ab7f24
Y.Wu et al. (2016) Green and biodegradable composite films with novel antimicrobial performance based on cellulose , Food Chem., 197, 250-256.
https://doi.org/10.1016/j.foodchem.2015.10.127
V.Rathi, V.Panwar, G.Anoop, M.Chaturvedi, K. Sharma, B.Prasad (2019) Flexible, Thin Composite Film to Enhance the Electromagnetic Compatibility of Biomedical Electronic Devices, IEEE Trans. Electromagn. Compat., 61, 1033-1041.
https://doi.org/10.1109/TEMC.2018.2881267
L.Wang, Z.Ma, Y.Zhang, H.Qiu, K.Ruan, J.Gu (2022) Mechanically strong and folding‐endurance Ti3C2Tx MXene/PBO nanofiber films for efficient electromagnetic interference shielding and thermal management, Carbon Energy, 4, 200-210.
https://doi.org/10.1002/cey2.174
D.Suman, N.Karna, B.P.Sahoo (2019) Development of Poly (vinylidene fluoride) and Polyaniline blend with high dielectric permittivity, excellent electromagnetic shielding effectiveness and Ultra low optical energy band gap: Effect of ionic liquid and temperature, Polymer, 181, 121759.
https://doi.org/10.1016/j.polymer.2019.121759
A.A.Shamsuri, R.Daik (2015) Application of ionic liquids and their mixtures for preparation of advanced polymer blends and composites: a short review, Rec. Adv. in Matr. Sci., 40, 45-59.
A.Gupta, M.Jain, M.Kumari, S.K.Tripathi (2021) Electrical, electrochemical and structural studies of a chlorine-derived ionic liquid-based polymer gel electrolyte, Beilstein J. Nanotechnol., 12, 1252-1261.
https://doi.org/10.3762/bjnano.12.92
K.-W. Yeung, C.-Y.Tang, W.-C.Law, G.C.-P.Tsui, X. Xie (2021) Development of ionic liquid-based electroactive polymer composites using nanotechnology, Nanotechnol. Rev., 10, 99-116.
https://doi.org/10.1515/ntrev-2021-0009
A.A.Shamsuri, S.N.A.Md. Jamil, K.Abdan (2021) A Brief Review on the Influence of Ionic Liquids on the Mechanical, Thermal, and Chemical Properties of Biodegradable Polymer Composites, Polymers, 13, 2597.
https://doi.org/10.3390/polym13162597
S.B.Aziz, M.F.Z. Kadir, M.H.Hamsan, H.J.Woo, M. A. Brza (2019) Development of Polymer Blends Based on PVA:POZ with Low Dielectric Constant for Microelectronic Applications. Sci. Rep., 9, 13163.
https://doi.org/10.1038/s41598-019-49715-8
L.Wang, C.Liu, S.Shen, M.Xu, X.Liu (2020) Low dielectric constant polymers for high speed communication network, Adv.Ind.Eng.Polym.Res., 3, 138-148.
https://doi.org/10.1016/j.aiepr.2020.10.001
K.Qian, R.Qiao, S.Chen, H.Luo, D.Zhang (2020) Enhanced permittivity in polymer blends via tailoring the orderliness of semiconductive liquid crystalline polymers and intermolecular interactions J. Mater. Chem.C, 8, 8440-8450.
https://doi.org/10.1039/D0TC00766H
R.J.Sengwa, P.Dhatarwal (2021) PVA/MMT and (PVA/PVP)/MMT hybrid nanocomposites for broad-range radio frequency tunable nanodielectric applications, Mater. Lett., 299, 130081.
https://doi.org/10.1016/j.matlet.2021.130081
P.Dhatarwal, R.J.Sengwa (2020) Structural and dielectric characterization of (PVP/PEO)/Al2O3 nanocomposites for biodegradable nanodielectric applications, Adv. Compos. Hybrid Mater., 3, 344-353.
https://doi.org/10.1007/s42114-020-00168-y
S.Jha, V.Bhavsar, K.P.Sooraj, M.Ranjan, D. Tripathi (2021) Investigation of the effect of in-situ grown PPy on low frequency dielectric properties and other properties of PVA-PVP blend film, J. Adv. Dielectr., 11, 2150020.
https://doi.org/10.1142/S2010135X2150020X
S.H.Deshmukh, D.K.Burghate, V.P.Akhare, V.S. Deogaonkar, P.T.Deshmukh, M.S.Deshmukh (2007) Electrical conductivity of polyaniline doped PVC-PMMA polymer blends, Bull. Mater. Sci., 30, 51-56.
https://doi.org/10.1007/s12034-007-0009-6
I.Noshadi et al. (2017) Engineering Biodegradable and Biocompatible Bio-ionic Liquid Conjugated Hydrogels with Tunable Conductivity and Mechanical Properties, Sci. Rep., 7, 4345-4363.
https://doi.org/10.1038/s41598-017-04280-w
S.Ahmad, S.Ahmad, S.A.Agnihotry (2007) Synthesis and characterization of in situ prepared poly (methyl methacrylate) nanocomposites, Bull. Mater. Sci., 30, 31-35.
https://doi.org/10.1007/s12034-007-0006-9
M.Faisal, S.Khasim (2013) Electrical Conductivity, Dielectric Behavior and EMI Shielding Effectiveness of Polyaniline-Yttrium Oxide Composites, Bull. Korean Chem. Soc., 34, 99-106.
https://doi.org/10.5012/bkcs.2013.34.1.99
F.Elhi et al. (2020) Understanding the Behavior of Fully Non-Toxic Polypyrrole-Gelatin and Polypyrrole-PVdF Soft Actuators with Choline Ionic Liquids, Actuators, 9, 40-57.
https://doi.org/10.3390/act9020040
E.L.Bennett, C.Song, Y.Huang, J.Xiao (2019) Measured relative complex permittivities for multiple series of ionic liquids, J. Mol. Liq., 294, 111571.
https://doi.org/10.1016/j.molliq.2019.111571
D.M.Correia et al. (2020) Ionic Liquid-Polymer Composites: A New Platform for Multifunctional Applications, Adv. Funct. Mater., 30, 1909736.
https://doi.org/10.1002/adfm.201909736
V.Bhavsar, D.Tripathi (2020) Study of biocompatible polymer blend films with tuneable band gap, Indian J of Pure and App Phy. 58, 795-803.
L.Xue et al.(2013) Choline acetate enhanced the catalytic performance of Candida rogusa lipase in AOT reverse micelles, Colloids Surf. B Biointerfaces, 105, 81-86.
https://doi.org/10.1016/j.colsurfb.2012.12.050
E.Håkansson, A.Amiet, A.Kaynak (2006) Electromagnetic shielding properties of polypyrrole/polyester composites in the 1-18GHz frequency range, Synth. Met., 156, 917-925.
https://doi.org/10.1016/j.synthmet.2006.05.010
D.D.Ateh, H.A.Navsaria, P.Vadgama (2006) Polypyrrole-based conducting polymers and interactions with biological tissues, J. R. Soc. Interface, 3, 741-752.
https://doi.org/10.1098/rsif.2006.0141
R.Balint, N.J.Cassidy, S.H.Cartmell (2014) Conductive polymers: Towards a smart biomaterial for tissue engineering, Acta Biomater., 10, 2341-2353.
https://doi.org/10.1016/j.actbio.2014.02.015
A.Rawat, H.K.Mahavar, S.Chauhan, A.Tanwar, P. Singh (2012) Optical band gap of polyvinylpyrrolidone/polyacrilamide blend thin films, Indian J of Pure and App Phy., 50,100-104, https://www.semanticscholar.org/paper/Optical-band-gap-of-blend-thin-films-Rawat-Mahavar/ 2cecd86c7d3cb376ae43a69092772dbd7a908766
D.Mondal et al (2013) Effect of poly(vinyl pyrrolidone) on the morphology and physical properties of poly(vinyl alcohol)/sodium montmorillonite nanocomposite films, Prog. Nat. Sci.Mater.Int., 23, 579-587.
https://doi.org/10.1016/j.pnsc.2013.11.009
M.Altenhofen da Silva, M.G.Adeodato Vieira, A.C. Gomes Maçumoto, M.M.Beppu (2011) Polyvinylchloride (PVC) and natural rubber films plasticized with a natural polymeric plasticizer obtained through polyesterification of rice fatty acid, Polym. Test., 30, 478-484.
https://doi.org/10.1016/j.polymertesting.2011.03.008
D.-J.Tao, Z.Cheng, F.-F.Chen, Z.-M.Li, N.Hu, X.-S. Chen (2013) Synthesis and Thermophysical Properties of Biocompatible Cholinium-Based Amino Acid Ionic Liquids, J.Chem.Eng.Data, 58, 1542-1548.
https://doi.org/10.1021/je301103d
B.L.Gadilohar, G.S.Shankarling (2017) Choline based ionic liquids and their applications in organic transformation, J.Mol.Liq., 227, 234-261.
https://doi.org/10.1016/j.molliq.2016.11.136
V.Bhavsar, D.Tripathi (2017) Study of attenuation of microwaves by PPy-Doped PVC films, Polym. Eng. Sci., 57, 89-94.
https://doi.org/10.1002/pen.24388
H.R.Hafiz (1996), Aspects on the percolation and conduction behavior in polypyrrole-poly (vinyl chloride) composite, Polym. Bull., 37, 647-654.
https://doi.org/10.1007/BF00296611
S.Jayanthi (2019) Studies on ionic liquid incorporated polymer blend electrolytes for energy storage applications, Adv. Compos. Hybrid Mater., 2, 351-360.
https://doi.org/10.1007/s42114-019-00102-x
P.-H.Wang, T.-L.Wang, W.-C.Lin, H.-Y.Lin, M.-H. Lee, C.-H.Yang (2018) Crosslinked Polymer Ionic Liquid/Ionic Liquid Blends Prepared by Photopolymerization as Solid-State Electrolytes in Supercapacitors, Nanomaterials, 8, 225-242.
https://doi.org/10.3390/nano8040225
M.Ravindar Reddy, A.Mallikarjun, M.J.Reddy, A. R.Subrahmanyam, M.V.Reddy (2021) Investigation of morphology and transport properties of Na + ion conducting PMMA:PEO hybrid polymer electrolyte, J. Polym. Eng., 41, 654-659.
https://doi.org/10.1515/polyeng-2020-0346
K.Subramaniam, A.Das, D.Steinhauser, M.Klüppel, G.Heinrich (2011) Effect of ionic liquid on dielectric, mechanical and dynamic mechanical properties of multi-walled carbon nanotubes/ polychloroprene rubber composites, Eur.Polym.J., 47, 2234-2243.
https://doi.org/10.1016/j.eurpolymj.2011.09.021
S.Choudhary, R.J.Sengwa (2016) Structural dynamics and ionic conductivity of amorphous type plasticized solid polymer electrolytes, APPL PHYS, 54, 159-169.
A.Yussuf, M.Al-Saleh, S.Al-Enezi, G.Abraham (2018) Synthesis and Characterization of Conductive Polypyrrole: The Influence of the Oxidants and Monomer on the Electrical, Thermal, and Morphological Properties, Int. J. Polym. Sci., 2018, ID 4191747.
https://doi.org/10.1155/2018/4191747
M.D.Migahed, M.Ishra, T.Fahmy, A.Barakat (2004) Electric modulus and AC conductivity studies in conducting PPy composite films at low temperature, J.Phys.Chem.Solids, 65, 1121-1125.
https://doi.org/10.1016/j.jpcs.2003.11.039
A.Gupta, A.Jain, S.K.Tripathi (2021) Structural, electrical and electrochemical studies of ionic liquid-based polymer gel electrolyte using magnesium salt for supercapacitor application, J. Polym. Res., 28, 235.
https://doi.org/10.1007/s10965-021-02597-9
O.Gh.Abdullah, R.R.Hanna, H.T.Ahmed, A.H. Mohamad, S.A.Saleem, M.A.M.Saeed (2021) Conductivity and dielectric properties of lithium-ion biopolymer blend electrolyte based film, Results Phys., 24,104135.
https://doi.org/10.1016/j.rinp.2021.104135
P.Wang, P.Xu, Y.Zhou, Y.Yang, Y.Ding (2018) Effect of MWCNTs and P[MMA-IL] on the crystallization and dielectric behavior of PVDF composites, Eur. Polym. J., 99, 58-64.
https://doi.org/10.1016/j.eurpolymj.2017.12.003
D.A.Nasrallah, M.A.Ibrahim (2022) Enhancement of physico-chemical, optical, dielectric and anti-microbial properties of polyvinyl alcohol/ carboxymethyl cellulose blend films by addition of silver doped hydroxyapatite nanoparticles, J. Polym. Res., 29, 86.
